Establishing electro-functionalized gravity-driven ceramic membrane filtration (EGDCM) for decentralized treatment of algae-laden brackish water: Comparison of in-situ electro-oxidation and ex-situ electro-coagulation.

Algae-laden brackish water (ABW) has remarkably threatened drinking water safety in warm coastal areas. Although gravity-driven ceramic membrane filtration (GDCM) exhibits high potential in ABW treatment during decentralized water supply, membrane fouling is still a critical problem. Herein, GDCM was skillfully electro-functionalized (EGDCM) by in-situ electro-oxidation (ISEO) based on self-fabricated Ti/SnO-Sb dimensionally stable anode (DSA) (EO-EGDCM) and ex-situ electro-coagulation (ESEC) based on iron anode (EC-EGDCM) in this study. EO-EGDCM with KMnO augment (MnEO-EGDCM) was also established for comparison. Results show that ISEO increased GDCM membrane permeability by 22 %, while EC-EGDCM membrane flux was nearly 4.8 times that of GDCM. ISEO enhanced the early removal of organic pollution, and KMnO facilitated the active chlorine oxidization of ammonia and algal toxins on electrified Ti/SnO2-Sb DSA by suppressing the transformation of free chlorine to less reactive chloramines. Both algae cell permeabilization and intracellular organic matter release were enhanced by ISEO. But SEM-EDS, CLSM and biomass analysis evidenced that membrane biological process, which was improved by 32 %∼323 % by electrical stimulation, developed porous structures in the fouling layer in EO-EGDCM/MnEO-EGDCM. According to energy consumption and carbon emissions evaluation, GDCM was confirmed as an energy-saving system for treating ABW with the consumption of only 3.47 × 10 kWh/m. Electricity demand was increased for EGDCM but still considerably lower than that for other algae-laden water treatment processes. EC-EGDCM reduced energy consumption and carbon emission by around 80 % compared to EC-EGDCM/MnEO-EGDCM. Electro-functionalization was a promising option to improve GDCM treatment of ABW via multiple mechanisms but further optimization was still required.