Active Particles Knead Three-Dimensional Gels into Porous Structures.

Colloidal gels are prime examples of functional materials exhibiting disordered, amorphous, yet metastable forms. They maintain stability through short-range attractive forces and their material properties are tunable by external forces. Combining persistent homology analyses and simulations of three-dimensional colloidal gels doped with active particles, we reveal novel dynamically evolving structures of colloidal gels. Specifically, we show that the local injection of energy by active dopants can lead to highly porous, yet compact gel structures that can significantly affect the transport of active particles within the modified colloidal gel. We further show how passive interfaces play a topologically significant role in interacting with active particles in 3D. The results open the door to an unexplored prospect of forming a wide variety of compact but highly heterogeneous and percolated porous media through active doping of 3D passive matter, with diverse implications in designing new functional materials for active ground remediation.