Demirel Bayik Gülçin, Baykal Busenur
Department of Environmental Engineering, Faculty of Engineering, Zonguldak Bulent Ecevit University, Zonguldak 67000, Turkey.
Nanomaterials (Basel). 2024 Dec 5;14(23):1954. doi: 10.3390/nano14231954.
The choice of plant species is crucial, as different plants provide unique biomolecules that influence nanoparticle characteristics. Biomolecules in plant extracts, such as proteins, amino acids, enzymes, polysaccharides, alkaloids, tannins, phenolics, saponins, terpenoids, and vitamins, act as stabilizing and reducing agents. This study explores the synthesis of silver nanoparticles (AgNPs) using leaf extracts from collard greens ( var. ), hazelnut ( var. ), and green tea (). NPs were synthesized using silver nitrate (AgNO) solution at two different molarities (1 mM and 5 mM) and characterized by UV-Vis spectroscopy, XRD, TEM, and FTIR. The Surface Plasmon Resonance (SPR) peaks appeared rapidly for hazelnut and green tea extracts, within 30 and 15 min, respectively, while collard greens extract failed to produce a distinct SPR peak. X-Ray Diffraction confirmed the formation of face-centered cubic silver. TEM analysis revealed high polydispersity and agglomeration in all samples, with particle size generally decreasing at higher AgNO concentrations. However, hazelnut extract showed a slight increase in size at higher molarity. Among all samples, green tea-derived AgNPs synthesized with 5 mM AgNO were the smallest and least polydisperse, highlighting the significant role of plant type in optimizing nanoparticle synthesis.
植物种类的选择至关重要,因为不同的植物会提供影响纳米颗粒特性的独特生物分子。植物提取物中的生物分子,如蛋白质、氨基酸、酶、多糖、生物碱、单宁、酚类、皂苷、萜类化合物和维生素,可作为稳定剂和还原剂。本研究探索了使用羽衣甘蓝(变种 )、榛子(变种 )和绿茶( )的叶子提取物合成银纳米颗粒(AgNP)。使用两种不同摩尔浓度(1 mM和5 mM)的硝酸银(AgNO)溶液合成纳米颗粒,并通过紫外可见光谱、X射线衍射、透射电子显微镜和傅里叶变换红外光谱对其进行表征。榛子和绿茶提取物的表面等离子体共振(SPR)峰分别在30分钟和15分钟内迅速出现,而羽衣甘蓝提取物未能产生明显的SPR峰。X射线衍射证实了面心立方银的形成。透射电子显微镜分析显示所有样品都具有高多分散性和团聚现象,在较高的AgNO浓度下粒径通常会减小。然而,榛子提取物在较高摩尔浓度下粒径略有增加。在所有样品中,用5 mM AgNO合成的绿茶衍生的AgNP最小且多分散性最低,突出了植物类型在优化纳米颗粒合成中的重要作用。
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