Influence of Relative Humidity on the Mechanical Properties of Palm Leaf Manuscripts: Short-Term Effects and Long-Term Aging.

Palm leaf manuscripts are a valuable part of world cultural heritage. Studying the mechanical properties of palm leaf manuscripts and their changes due to environmental influences is of great significance for understanding the material characteristics, aging mechanisms, and preventive conservation of these manuscripts. This study used dynamic vapor sorption (DVS) and a thermomechanical analyzer (TMA) to investigate the changes to the mechanical properties of palm leaf manuscripts in response to different relative humidity conditions and different time periods. The short-term study results show that exposure to varying relative humidities leads to changes in the equilibrium moisture content (EMC) of palm leaf manuscripts, causing the bending strength of the samples to decrease significantly with increasing humidity. The bending modulus initially increases and then decreases as the humidity increases. Moreover, the greater the desorption hysteresis of the samples, the more pronounced the changes to the mechanical properties. Therefore, a stable environment in terms of humidity can prevent changes in the mechanical properties of palm leaf manuscripts, thereby preventing the onset of degradation. The results of the long-term aging studies indicate that prolonged exposure to either very dry or very humid conditions greatly affects the mechanical properties of palm leaf manuscripts, which is detrimental to their preservation. The samples kept at 50% RH did not exhibit significant signs of deterioration, with no notable changes in their mechanical properties or chemical structure. This suggests that 50% RH is a relatively optimal humidity condition for the preservation of palm leaf manuscripts.