Li Ying, Yu Mingyang, Li Xiwu, Wen Kai, Yan Lizhen, Zhu Kai, Xiao Wei
State Key Laboratory of Nonferrous Metals and Processes, GRINM Group Co., Ltd., Beijing 100088, China.
GRIMAT Engineering Institute Co., Ltd., Beijing 101407, China.
Materials (Basel). 2024 Nov 21;17(23):5678. doi: 10.3390/ma17235678.
The 7085 aluminum alloy with a low Cu content is an important lightweight structural material in the aerospace field due to its advantages of low density, high specific strength, and high hardenability. However, like other high-strength Al-Zn-Mg-Cu alloys, this alloy is susceptible to stress corrosion cracking (SCC). Additionally, the lower Cu content may increase its tendency toward SCC, potentially impacting the safe use of this alloy. Therefore, this study investigated the effects of aging treatment processes on the mechanical properties and SCC resistance of 7085 aluminum alloy. And the factors affecting the properties of the alloy were analyzed by optical microscope (OM), scanning transmission electron microscope (STEM), and energy-dispersive X-ray spectroscopy (EDS) analyses. The results indicated that increasing the secondary aging temperature and adding a tertiary aging step can significantly reduce the alloy's susceptibility to SCC while meeting the mechanical performance requirements. The reduced SCC sensitivity was mainly attributed to the increased spacing of grain boundary precipitates, a wider precipitate-free zone at the grain boundaries, and a higher Cu content in the grain boundary precipitates.
低铜含量的7085铝合金因其低密度、高比强度和高淬透性等优点,是航空航天领域重要的轻质结构材料。然而,与其他高强度Al-Zn-Mg-Cu合金一样,该合金易发生应力腐蚀开裂(SCC)。此外,较低的铜含量可能会增加其SCC倾向,潜在影响该合金的安全使用。因此,本研究调查了时效处理工艺对7085铝合金力学性能和抗SCC性能的影响。并通过光学显微镜(OM)、扫描透射电子显微镜(STEM)和能量色散X射线光谱(EDS)分析,分析了影响合金性能的因素。结果表明,提高二次时效温度并增加三次时效步骤,可在满足力学性能要求的同时,显著降低合金的SCC敏感性。SCC敏感性降低主要归因于晶界析出相间距增加、晶界处无析出区变宽以及晶界析出相中铜含量增加。