Form-Stable Phase-Change Materials Using Chemical Vapor Deposition-Derived Porous Supports: Carbon Nanotube/Diatomite Hybrid Powder and Carbon Nanotube Sponges.

In this work, two types of chemical vapor deposition (CVD)-derived porous supporting materials consisting of CNTs-decorated diatomite (CNT/DE) and CNT sponges (CNS) were developed to prepare novel form-stable phase-change material (PCM) composites by impregnation, using polyethylene glycol (PEG) as the PCM. The CNT/DE support matrix showed highly entangled nanotubes (the weight ratio of CNTs to DE was 0.16) over and inside the porous structure of diatomite, giving the hybrid matrix an electrical response. The CNS that resulted was mainly composed of bent and interconnected CNTs forming a three-dimensional highly porous structure. XPS and FTIR results revealed that CNTs in both the supporting materials have a moderate amount of oxygen-containing functional groups. Both hosts allow for high PEG loading (about 75 wt%) without showing any PCM leakage during melting. Both form-stable PCM composites showed high thermal reliability upon a hundred melting-solidification DSC cycles (PEG/CNT/DE latent heat is 86 ± 4 J/g and PEG/CNS latent heat is 100 ± 2 J/g; melting temperature 34 °C). An analytical model was used to evaluate the passive cooling performance of the systems, simulating the thermal behaviour of a building wall containing the confined PCM in the hosts, resulting in a reduction in required cooling power of about 10%. The overall results suggest that the developed form-stable PCM composites could be considered promising additive materials for the production of building envelopes with thermal energy storage capability.