Lin Jinhan, Hu Xueyang, Tan Xuechao, Zhang Yan, Lin Chunxi, Shan Wenpo, He Hong
Center for Excellence in Regional Atmospheric Environment and Key Laboratory of Urban Pollutant Conversion, Institute of Urban Environment, Chinese Academy of Science, Xiamen 361021, China.
Zhejiang Key Laboratory of Pollution Control for Port-Petrochemical Industry, Ningbo Urban Environment Observation and Research Station, Institute of Urban Environment, Chinese Academy of Sciences, Ningbo 315800, China.
Environ Sci Technol. 2025 Jan 28;59(3):1864-1874. doi: 10.1021/acs.est.4c09820. Epub 2024 Dec 19.
For Cu-exchanged zeolite catalysts, Cu ions existing as Cu-2Z and [Cu(OH)]-Z (where Z represents a framework negative charge) are considered the active sites for the selective catalytic reduction of NO with NH (NH-SCR). Cu-2Z is more hydrothermally stable and sulfur poisoning-resistant than [Cu(OH)]-Z. In this work, Cu-CHA and Cu-LTA catalysts containing only Cu-2Z species were successfully synthesized by a novel impregnation (NIM) method, exhibiting remarkably enhanced hydrothermal stability and sulfur resistance compared with any reported Cu-exchanged zeolite catalysts. It was also found that the [Cu(OH)]-Z sites can convert to Cu-2Z by treating at high temperature (850 °C) due to the self-reduction of Cu to highly mobile Cu. The use of the NIM method not only significantly simplifies the preparation of the catalysts but also can precisely control the Cu loading, which is very important for the control of Cu species. Many other zeolite catalysts can be prepared by this method.
