Chiroptical Synaptic Perovskite Memristor as Reconfigurable Physical Unclonable Functions.

Physical unclonable functions (PUFs), often referred to as digital fingerprints, are emerging as critical elements in enhancing hardware security and encryption. While significant progress has been made in developing optical and memory-based PUFs, integrating reconfigurability with sensitivity to circularly polarized light (CPL) remains largely unexplored. Here, we present a chiroptical synaptic memristor (CSM) as a reconfigurable PUF, leveraging a two-dimensional organic-inorganic halide chiral perovskite. The device combines CPL sensitivity with photoresponsive electrical behavior, enabling its application in optoneuromorphic systems, as demonstrated by its ability to perform image categorization tasks within neuromorphic computing. Furthermore, by leveraging a 10 × 10 crossbar array of the CSMs, we develop a PUF capable of generating reconfigurable cryptographic keys based on the combination of neuromorphic potentiation and polarized light conditions. This work demonstrates an integrated approach to optoneuromorphic functionality, data storage, and encryption, providing an alternative approach for reconfigurable memristor-based PUFs.