Optimization of the Zinc Deposition Interface by Sn Nanoparticles for Fast-Charging Zinc Metal Anodes.

The electrodeposition behavior of zinc metal anodes critically correlates with the electrode surface properties. The tendency for inhomogeneous deposition of zinc is more severe, especially under high current density. Herein, the surface structure of zinc and zinc deposition substrates is reconstructed with a uniform metal tin (Sn) coating via a simple evaporation method. Sn nanoparticles can serve on metal nuclei to reduce the Zn nucleation barrier and enable more nucleation sites for even deposition. Moreover, the mechanical stability of the electrode surface is improved via Zn-Sn alloying. Consequently, the uniform Zn deposition/dissolution behavior on Sn-modified two- and three-dimensional copper substrates is reflected in the stable Coulombic efficiency and reduced polarization. The Sn@Zn electrode is endowed with superior stability at a high current density (800 h at 20 mA cm). More encouragingly, the full cell installed with a carbon nanotube/MnO cathode maintains enduring stability (700 cycles) at 1 A g. This work enlightens metal alloy as an effective and instructive modification strategy toward stabilized zinc anodes.