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对土耳其东南部两座原油生产厂大气挥发性有机化合物的评估。

Assessment of atmospheric volatile organic compounds at two crude oil production plants in Southeastern Türkiye.

作者信息

Koçak Talha Kemal, Günal Aysel Çağlan

机构信息

Graduate School of Natural and Applied Sciences, Gazi University, Ankara, 06500, Türkiye.

出版信息

Environ Monit Assess. 2024 Dec 21;197(1):88. doi: 10.1007/s10661-024-13494-1.

DOI:10.1007/s10661-024-13494-1
PMID:39708270
Abstract

Ambient Volatile Organic Compounds (VOCs) were investigated to determine their characteristics, Ozone Formation Potentials (OFPs), and health risks in two crude oil production plants (Nusaybin and Egil plants) in southeastern Türkiye. Benzene, toluene, ethylbenzene, m + p xylene, o xylene, and 1,3,5-trimethylbenzene were measured at eight passive sampling points in each plant. Samples were analyzed using gas chromatography coupled with a flame ionization detector and a thermal desorption. The concentration of ranged from 5.03 to 88.43 μg/m in the Nusaybin Plant and from 7.70 to 154.35 μg/m in the Egil Plant. Toluene and xylenes were predominant in both plants. In the Nusaybin Plant, VOCs were mainly associated with crude oil production, while in the Egil Plant, they were associated with a combination of crude oil production and mobile vehicle activities. The OFP of was 297.47 μg/m in the Nusaybin Plant, and 249.25 μg/m in the Egil Plant. M + p xylene, toluene, and 1,3,5-trimethylbenzene together contributed 86% and 84% of the total OFP in the Nusaybin and Egil plants, respectively. Benzene exposure posed a possible cancer risk to oil workers in both plants. Non-cancer health risk was at a potential level in the Egil Plant but negligible in the Nusaybin Plant. This study is expected to enhance knowledge regarding the effects of crude oil production plants on air quality and workplace exposure.

摘要

对土耳其东南部两座原油生产厂(努赛宾厂和埃吉尔厂)的环境挥发性有机化合物(VOCs)进行了调查,以确定其特征、臭氧生成潜势(OFP)和健康风险。在每个工厂的八个被动采样点测量了苯、甲苯、乙苯、间二甲苯+对二甲苯、邻二甲苯和1,3,5-三甲苯。使用气相色谱仪结合火焰离子化检测器和热脱附对样品进行分析。努赛宾厂的浓度范围为5.03至88.43μg/m³,埃吉尔厂的浓度范围为7.70至154.35μg/m³。甲苯和二甲苯在两个工厂中均占主导地位。在努赛宾厂,VOCs主要与原油生产有关,而在埃吉尔厂,它们与原油生产和移动车辆活动的组合有关。努赛宾厂的OFP为297.47μg/m³,埃吉尔厂为249.25μg/m³。间二甲苯+对二甲苯、甲苯和1,3,5-三甲苯分别占努赛宾厂和埃吉尔厂总OFP的86%和84%。苯暴露对两个工厂的石油工人都构成了可能的癌症风险。非癌症健康风险在埃吉尔厂处于潜在水平,但在努赛宾厂可忽略不计。本研究有望增进对原油生产厂对空气质量和工作场所暴露影响的认识。

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