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Synthesis and structure of -2,5-di-methyl-piperazine-1,4-diium di-hydrogen diphosphate.

作者信息

Mrad Houda, Elboulali Adel, Baptiste Benoît, Akriche Samah

机构信息

Laboratory of Materials Chemistry (LR13ES08), Faculty of Sciences of Bizerte, University of Carthage, 7021 Zarzouna, Bizerte, Tunisia.

Institut de Minéralogie, de Physique des Matériaux et de, Cosmochimie CNRS - UMR 7590, Plateforme de diffraction des rayons X, 75005 Paris, France.

出版信息

Acta Crystallogr E Crystallogr Commun. 2024 Oct 24;80(Pt 11):1202-1205. doi: 10.1107/S2056989024010132. eCollection 2024 Oct 1.

DOI:10.1107/S2056989024010132
PMID:39712168
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11660472/
Abstract

In the title salt, CHN ·HPO , the complete dication is generated by a crystallographic centre of symmetry with the methyl groups in equatorial orientations. The complete dianion is generated by a crystallographic twofold axis with the central O atom lying on the axis: the P-O-P bond angle is 135.50 (12)°. In the crystal, the di-hydrogen diphosphate anions are linked by O-H⋯O hydrogen bonds, generating (001) layers. The organic cations bond to the inorganic layers by way of N-H⋯O and C-H⋯O hydrogen bonds. A Hirshfeld surface analysis shows that the most important contributions for the crystal packing are from O⋯H/H⋯O (60.5%) and H⋯H (39.4%) contacts.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32b0/11660472/6124c67b136f/e-80-01202-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32b0/11660472/a7a39a429dc9/e-80-01202-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32b0/11660472/c23b6835c24f/e-80-01202-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32b0/11660472/fdb97367467e/e-80-01202-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32b0/11660472/a80511b65a32/e-80-01202-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32b0/11660472/6124c67b136f/e-80-01202-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32b0/11660472/a7a39a429dc9/e-80-01202-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32b0/11660472/c23b6835c24f/e-80-01202-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32b0/11660472/fdb97367467e/e-80-01202-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32b0/11660472/a80511b65a32/e-80-01202-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32b0/11660472/6124c67b136f/e-80-01202-fig5.jpg

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2
trans-2,5-Di-methyl-piperazine-1,4-diium dinitrate.反式-2,5-二甲基哌嗪-1,4-二铵二硝酸盐
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