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生物质衍生平台化学品的光化学反应。

Photochemical reactions of biomass derived platform chemicals.

作者信息

Hoffmann Norbert, Gomez Fernandez Mario Andrés, Desvals Arthur, Lefebvre Corentin, Michelin Clément, Latrache Mohammed

机构信息

Institut de Physique et de Chimie des Matériaux de Strasbourg (IPCMS), CNRS, Université de Strasbourg, UMR 7504, Strasbourg, France.

Laboratoire de Glycochimie et des Agroressources d'Amiens (LG2A), Université de Picardie Jules Verne (UPJV), Amiens, France.

出版信息

Front Chem. 2024 Dec 10;12:1485354. doi: 10.3389/fchem.2024.1485354. eCollection 2024.

DOI:10.3389/fchem.2024.1485354
PMID:39720554
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11666374/
Abstract

Platform chemicals obtained from biomass will play an important role in chemical industry. Already existing compounds or not yet established chemicals are produced from this renewable feedstock. Using photochemical reactions as sustainable method for the conversion of matter furthermore permits to develop processes that are interesting from the ecological and economical point of view. Furans or levoglucosenone are thus obtained from carbohydrate containing biomass. Photochemical rearrangements, photooxygenation reactions or photocatalytic radical reactions can be carried out with such compounds. Also, sugars such pentoses or hexoses can be more easily transformed into heterocyclic target compounds when such photochemical reactions are used. Lignin is an important source for aromatic compounds such as vanillin. Photocycloaddition of these compounds with alkenes or the use light supported multicomponent reactions yield interesting target molecules. Dyes, surfactants or compounds possessing a high degree of molecular diversity and complexity have been synthesized with photochemical key steps. Alkenes as platform chemicals are also produced by fermentation processes, for example, with cyanobacteria using biological photosynthesis. Such alkenes as well as terpenes may further be transformed in photochemical reactions yielding, for example, precursors of jet fuels.

摘要

从生物质中获取的平台化学品将在化学工业中发挥重要作用。这种可再生原料可生产现有化合物或尚未确定的化学品。将光化学反应用作物质转化的可持续方法，还能开发出从生态和经济角度来看都很有吸引力的工艺。因此，呋喃或左旋葡聚糖酮可从含碳水化合物的生物质中获得。此类化合物可进行光化学重排、光氧化反应或光催化自由基反应。此外，当使用此类光化学反应时，戊糖或己糖等糖类能更轻松地转化为杂环目标化合物。木质素是香草醛等芳香化合物的重要来源。这些化合物与烯烃的光环加成反应或光辅助多组分反应可生成有趣的目标分子。通过光化学关键步骤已合成了染料、表面活性剂或具有高度分子多样性和复杂性的化合物。烯烃作为平台化学品也可通过发酵过程生产，例如，利用蓝细菌通过生物光合作用生产。此类烯烃以及萜类化合物可进一步在光化学反应中转化，例如生成喷气燃料的前体。

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