Cao Yupeng, Lin Hui, Zong Tong, Xu Xiangbo, Li Mingdong, Bian Xia, Li Zhiqiang
College of Civil and Transportation Engineering, Weifang University, Weifang, 261061, China.
School of Civil & Architecture Engineering, East China University of Technology, Nanchang, 330013, China.
Sci Rep. 2024 Dec 30;14(1):31947. doi: 10.1038/s41598-024-83461-w.
The treatment and resource utilization of municipal sludge and dredged silt have been rendered urgent by the acceleration of urbanization and stricter environmental protection demands. An effective solution was developed to address the challenges of poor mechanical properties and the difficulty in directly using cement-based materials for municipal sludge treatment. The utilization of dredged silt with high water content served as the foundational skeleton material. Appropriate proportion (0.5:1.0) of sodium silicate, which accelerates cement hardening, and polyurethane, which facilitates chemical bond cooperation, was combined to form SP material, partially replacing cement. Unconfined compressive strength (UCS) tests were subsequently conducted on the solidified municipal sludge. These tests aimed to investigate the influence of the dredged silt mixing ratio, initial water content of dredged silt, and the SP mixing ratio on the strength of the solidified municipal sludge. Furthermore, a strength prediction model was established for solidified municipal sludge, taking into consideration the mixing ratios of dredged silt and SP. The research findings indicate that dredged silt can serve as a skeleton structure for solidified municipal sludge. The UCS of the solidified municipal sludge increases with the increase in the dredged silt mixing ratio, and reaches a maximum value at mixing ratio of 1.0. SP materials can partially replace cement, the appropriate proportion of SP and cement can synergistically improve the strength of solidified municipal sludge, and the optimal SP mixing ratio is 50%. Furthermore, the strength prediction model constructed with independent variables such as dredged silt mixing ratio, curing age, water-to-cement ratio, and SP mixing ratio demonstrates better predictability for the strength development of solidified municipal sludge.
城市化进程的加快和愈发严格的环境保护要求使得城市污泥和疏浚淤泥的处理及资源利用变得刻不容缓。针对城市污泥处理中水泥基材料力学性能差及直接使用困难的问题,开发了一种有效的解决方案。利用高含水量的疏浚淤泥作为基础骨架材料,将加速水泥硬化的硅酸钠和促进化学键协同作用的聚氨酯按适当比例(0.5:1.0)混合形成SP材料,部分替代水泥。随后对固化后的城市污泥进行无侧限抗压强度(UCS)试验,旨在研究疏浚淤泥掺量、疏浚淤泥初始含水量及SP掺量对固化城市污泥强度的影响。此外,考虑疏浚淤泥和SP的掺量,建立了固化城市污泥的强度预测模型。研究结果表明,疏浚淤泥可作为固化城市污泥的骨架结构。固化城市污泥的UCS随疏浚淤泥掺量的增加而增大,在掺量为1.0时达到最大值。SP材料可部分替代水泥,合适比例的SP与水泥协同作用可提高固化城市污泥的强度,最佳SP掺量为50%。此外,以疏浚淤泥掺量、养护龄期、水灰比和SP掺量等自变量构建的强度预测模型对固化城市污泥强度发展具有较好的预测能力。