Wu Peng, Zhang Lianying, Li Bing, Zheng Yadong, Li Ming, Zhu Fuqiang
School of Physics and New Energy, Xuzhou University of Technology, Xuzhou, 221018, China.
School of Civil Engineering, Xuzhou University of Technology, Xuzhou, 221018, China.
Sci Rep. 2024 Dec 30;14(1):32093. doi: 10.1038/s41598-024-83599-7.
To ensure the safe extraction of deep mineral resources, it is imperative to address the mechanical properties and damage mechanism of coal and rock media under the real-time coupling effect of high temperature and impact. In this study, the impact tests (impact velocities of 6.0-10.0 m/s) on coal-series limestone under real-time high-temperature conditions (25 °C-800 °C) were conducted by the real-time high-temperature split Hopkinson pressure bar (HT-SHPB) testing system, and the microscopic changes in mineral composition under the coupling effect of real-time high-temperature and high strain rate action were investigated by X-ray diffraction (XRD), electron scanning microscopy (SEM), energy dispersive spectroscopy (EDS). The results showed that the dynamic stress-strain curve of coal-series limestone under the real-time coupling effect of high temperature and impact during the compaction stage was not significant; As the impact velocity increases and the temperature increases, the plastic characteristics of the dynamic stress-strain curve become more notable, and the brittle failure of the sample is gradually changed into brittle-ductile failure. Additionally, the dynamic peak stress and dynamic elastic modulus exhibit distinct quadratic variations with the increased temperature, and the dynamic peak stress approximately increases linearly with the impact velocity. The main substances in coal-series limestone are calcite, dolomite, and muscovite. The microscopic morphology of calcite at room temperature is characterized by a thin stepped or layered structure. When the temperature rises to 800 °C, thermal decomposition rarely occurs in calcite, while its physical and mechanical properties undergo alternations. After real-time impact, the degree of crystal fragmentation of calcite increases and a large number of microcracks are generated. The dolomite exhibits a prismatic microscopic morphology at room temperature, characterized by distinct and flat edges, and typically occurs in clusters. When the temperature rises to 600 °C, an increased amount of dolomite initiates thermal decomposition, and the crystal edges become passive, even leading to the granulation phenomenon. Consequently, the impact mechanical properties of limestone are ultimately weakened due to the thermal decomposition of mineral components and changes in physical and mechanical properties caused by high temperature.
为确保深部矿产资源的安全开采,必须研究高温与冲击实时耦合作用下煤岩介质的力学特性及损伤机制。本研究采用实时高温分离式霍普金森压杆(HT-SHPB)试验系统,对煤系灰岩在实时高温条件(25℃-800℃)下进行冲击试验(冲击速度为6.0-10.0m/s),并通过X射线衍射(XRD)、电子扫描显微镜(SEM)、能谱分析(EDS)研究实时高温与高应变率耦合作用下矿物成分的微观变化。结果表明,煤系灰岩在高温与冲击实时耦合作用下压实阶段的动态应力-应变曲线变化不显著;随着冲击速度和温度的升高,动态应力-应变曲线的塑性特征更加明显,试样的脆性破坏逐渐转变为脆-韧性破坏。此外,动态峰值应力和动态弹性模量随温度升高呈现明显的二次变化,动态峰值应力随冲击速度近似线性增加。煤系灰岩中的主要物质为方解石、白云石和白云母。室温下方解石的微观形态为薄台阶状或层状结构。当温度升至800℃时,方解石很少发生热分解,但其物理力学性能发生变化。实时冲击后,方解石的晶体破碎程度增加,产生大量微裂纹。白云石在室温下呈现棱柱形微观形态,边缘清晰且平整,通常呈簇状出现。当温度升至600℃时,白云石热分解量增加,晶体边缘钝化,甚至出现粒化现象。矿物成分的热分解以及高温引起的物理力学性能变化最终削弱了灰岩的冲击力学性能。