Sun Yong, Feng Long, Xu Hongrui, Zhai Cheng, Tang Wei, Cong Yuzhou, Yu Xu, Xu Jizhao
School of Low Carbon Energy and Power Engineering, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China.
School of Safety Engineering, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China.
ACS Omega. 2024 Dec 12;9(51):50742-50757. doi: 10.1021/acsomega.4c08921. eCollection 2024 Dec 24.
Hot dry rock (HDR) is a novel green, low-carbon energy. Its development requires the creation of fracture channels in deep thermal reservoirs. Traditional methods such as hydraulic fracturing have limited effectiveness in reservoir stimulation, so a method of liquid nitrogen cold shock was proposed. The ultralow temperature of liquid nitrogen induces a quenching effect on hot rock, thereby promoting the formation of a complex fracture network. In this study, hot rocks at different temperatures were subjected to cyclic liquid nitrogen cold shocks. The cascading evolution of the "temperature field-thermal stress-pore fracture development-three-dimensional seepage network" was analyzed. The main conclusions are as follows: As the cold-shock duration increased, the core temperature decreased exponentially, with a slower cooling rate at the center and a faster rate at the edges. Additionally, local temperature fluctuations existed at the edges. The maximum radial thermal stress at 200-600 °C ranged from 2.57 to 9.29 MPa. The initial cold shock and temperatures above 300 °C contributed the most to the reduction in wave velocity, with maximum decreases of 70.25 and 55%, respectively. The more developed the pores and fractures within the damaged core, the more pronounced the arrival time lag, frequency shift, and energy attenuation will be. Microscopic pore evolution followed two patterns. At 200-300 °C, the first peak increased significantly, with a few new micropores forming along grain boundaries. At 400-600 °C, the second peak grew and expanded to be dominant. Numerous mesopores formed both along grain boundaries and within grain interiors, interconnecting with the original pores. As the temperature shock effect intensified, the fracture increased and expanded. Branch fractures developed from the main fractures, ultimately forming a fracture network. The orientations of these fractures became more randomly distributed. What's more, the proportion of larger-sized and higher-connectivity pores increased. The flow velocity and flow rate increased significantly, with the maximum values in the representative elementary volume reaching 0.167 m/s and 1.75 × 10 m/s, respectively. When HDR underwent liquid nitrogen cold shock, the mineral grains contracted. Due to the various thermal expansion coefficients of different types of grains, local stress was concentrated. When the stress exceeded the tensile strength, tensile fractures were induced. The cyclic shock effect not only intensified the stress concentration but also lowered the damage threshold of the grains. The convergence of these two factors led to the continuous development of pore-fracture channels in the HDR.
热干岩(HDR)是一种新型的绿色低碳能源。其开发需要在深部热储层中形成裂缝通道。水力压裂等传统方法在储层增产改造方面效果有限,因此提出了液氮冷冲击法。液氮的超低温对热岩石产生淬火效应,从而促进复杂裂缝网络的形成。在本研究中,对不同温度的热岩石进行了循环液氮冷冲击。分析了“温度场-热应力-孔隙裂缝发育-三维渗流网络”的 cascading 演化。主要结论如下:随着冷冲击持续时间的增加,岩芯温度呈指数下降,中心冷却速率较慢,边缘较快。此外,边缘存在局部温度波动。200-600℃时的最大径向热应力范围为2.57至9.29MPa。初始冷冲击和300℃以上的温度对波速降低的贡献最大,分别最大降低70.25%和55%。损伤岩芯内的孔隙和裂缝越发育,到达时间滞后、频移和能量衰减就越明显。微观孔隙演化遵循两种模式。在200-300℃时,第一个峰值显著增加,沿晶界形成一些新的微孔。在400-600℃时,第二个峰值增长并扩展为主导。沿晶界和晶粒内部均形成大量中孔,并与原始孔隙相互连通。随着温度冲击效应的增强,裂缝增加并扩展。分支裂缝从主裂缝发育而来,最终形成裂缝网络。这些裂缝的取向变得更加随机分布。此外,较大尺寸和较高连通性孔隙的比例增加。流速和流量显著增加,代表性单元体中的最大值分别达到0.167m/s和1.75×10m/s。当热干岩经历液氮冷冲击时,矿物颗粒收缩。由于不同类型颗粒的热膨胀系数不同,局部应力集中。当应力超过抗拉强度时,诱导产生拉伸裂缝。循环冲击效应不仅加剧了应力集中,还降低了颗粒的损伤阈值。这两个因素的共同作用导致热干岩中孔隙-裂缝通道的持续发育。 (注:原文中“1.75×10 m/s”表述似乎有误,可能影响准确理解,但按要求未做修改。)