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聚苯胺负载型有机转化催化剂综述

A Review on Polyaniline-Supported Catalyst for Organic Transformations.

作者信息

Behera Satyaranjan

机构信息

Department of Chemistry, Utkal University, Bhubaneswar 751004, India.

出版信息

ACS Omega. 2024 Dec 11;9(51):50097-50117. doi: 10.1021/acsomega.4c04352. eCollection 2024 Dec 24.

DOI:10.1021/acsomega.4c04352
PMID:39741858
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11683646/
Abstract

Organic transformations are very important in synthetic organic chemistry and are used immensely in pharmaceuticals. Polyaniline is a marvelous and exceptional conducting polymer because of its extensive and valuable applications. Various modified polyaniline derivatives were developed by researchers and explored as solid heterogeneous catalysts for synthesizing important organic compounds through different organic transformations. Polyaniline-supported catalysts have many advantages: easy synthesis, environmental stability, environmental friendliness, high yield, short reaction times, the requirement for green solvent or solventless medium, and excellent reusability. In past years, polyaniline-supported catalysts have been widely used in various important organic syntheses under solvent-free or green reaction conditions. Hence, here is a comprehensive, detailed review of the application of polyaniline catalysts in organic transformations with all of their advantages and future scope.

摘要

有机转化在有机合成化学中非常重要,在制药领域有大量应用。聚苯胺因其广泛而有价值的应用,是一种出色且特殊的导电聚合物。研究人员开发了各种改性聚苯胺衍生物,并将其作为固体多相催化剂,通过不同的有机转化来合成重要的有机化合物。聚苯胺负载型催化剂具有许多优点:易于合成、环境稳定性好、环境友好、产率高、反应时间短、对绿色溶剂或无溶剂介质有要求以及出色的可重复使用性。在过去几年中,聚苯胺负载型催化剂已在无溶剂或绿色反应条件下广泛用于各种重要的有机合成。因此,本文对聚苯胺催化剂在有机转化中的应用进行了全面、详细的综述,涵盖了它们的所有优点和未来发展前景。

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Recent advances in urea- and thiourea-containing compounds: focus on innovative approaches in medicinal chemistry and organic synthesis.含尿素和硫脲化合物的最新进展:聚焦于药物化学和有机合成中的创新方法。
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Preparations, Properties, and Applications of Polyaniline and Polyaniline Thin Films-A Review.
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Polymers (Basel). 2021 Jun 18;13(12):2003. doi: 10.3390/polym13122003.
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Polyaniline-Coated TiO Nanorods for Photocatalytic Degradation of Bisphenol A in Water.用于光催化降解水中双酚A的聚苯胺包覆二氧化钛纳米棒
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