• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

聚合物与多孔有机框架的共价整合。

Covalent integration of polymers and porous organic frameworks.

作者信息

Hossain Md Amjad, Coe-Sessions Kira, Ault Joe, Gboyero Felix O, Wenzel Michael J, Dhokale Bhausaheb, Davies Alathea E, Yang Qian, de Sousa Oliveira Laura, Li Xuesong, Hoberg John O

机构信息

Department of Chemistry, University of Wyoming, Laramie, WY, United States.

Center for Advanced Scientific Instrumentation, University of Wyoming, Laramie, WY, United States.

出版信息

Front Chem. 2024 Dec 18;12:1502401. doi: 10.3389/fchem.2024.1502401. eCollection 2024.

DOI:10.3389/fchem.2024.1502401
PMID:39744614
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11688193/
Abstract

Covalent integration of polymers and porous organic frameworks (POFs), including metal-organic frameworks (MOFs), covalent organic frameworks (COFs) and hydrogen-bonded organic frameworks (HOFs), represent a promising strategy for overcoming the existing limitations of traditional porous materials. This integration allows for the combination of the advantages of polymers, i.e., flexibility, processability and chemical versatility etc., and the superiority of POFs, like the structural integrity, tunable porosity and the high surface area, creating a type of hybrid materials. These resulting polymer-POF hybrid materials exhibit enhanced mechanical strength, chemical stability and functional diversity, thus opening up new opportunities for applications across a large variety of fields, such as gas separation, catalysis, biomedical applications, environmental remediation and energy storage. In this review, an overview of synthetic routes and strategies on how to covalently integrate different polymers with various POFs is discussed, especially with a particular focus on methods like polymerization within, on and among POF structures. To investigate the unique properties and functions of these resultant hybrid materials, the characterization techniques, including nuclear magnetic resonance spectroscopy (NMR), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), transmission electron microscopy (TEM) and scanning electron microscopy (SEM), gas adsorption analysis (BET) and computational modeling and machine learning, are also presented. The ability of polymer-POFs to manipulate the pore environments at the molecular level affords these materials a wide range of applications, providing a versatile platform for future advancements in material science. Looking forward, to fully realize the potential of these hybrid materials, the authors highlight the scalability, green synthesis methods, and potential for stimuli-responsive polymer-POF materials as critical areas for future research.

摘要

聚合物与多孔有机框架材料（POFs）的共价整合，包括金属有机框架材料（MOFs）、共价有机框架材料（COFs）和氢键有机框架材料（HOFs），是克服传统多孔材料现有局限性的一种很有前景的策略。这种整合能够将聚合物的优点，即柔韧性、可加工性和化学多功能性等，与POFs的优势，如结构完整性、可调孔隙率和高比表面积相结合，从而创造出一种混合材料。这些所得的聚合物-POF混合材料表现出增强的机械强度、化学稳定性和功能多样性，从而为气体分离、催化、生物医学应用、环境修复和能量存储等众多领域的应用开辟了新机遇。在这篇综述中，将讨论如何将不同聚合物与各种POFs进行共价整合的合成路线和策略概述，尤其特别关注诸如在POF结构内部、表面和之间进行聚合等方法。为了研究这些所得混合材料的独特性质和功能，还介绍了包括核磁共振光谱（NMR）、傅里叶变换红外光谱（FTIR）、X射线衍射（XRD）、热重分析（TGA）、透射电子显微镜（TEM）和扫描电子显微镜（SEM）、气体吸附分析（BET）以及计算建模和机器学习在内的表征技术。聚合物-POFs在分子水平上调控孔环境的能力赋予了这些材料广泛的应用，为材料科学的未来发展提供了一个通用平台。展望未来，为了充分实现这些混合材料的潜力，作者强调可扩展性、绿色合成方法以及刺激响应型聚合物-POF材料的潜力是未来研究的关键领域。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/b04e460c50ef/fchem-12-1502401-g025.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/43c46b887f23/fchem-12-1502401-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/678b6e61c376/fchem-12-1502401-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/42cd25ad68b7/fchem-12-1502401-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/1a91cef8a6be/fchem-12-1502401-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/f2ac3b38661d/fchem-12-1502401-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/68811d3a0751/fchem-12-1502401-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/7a0aac6dc988/fchem-12-1502401-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/a74a786af245/fchem-12-1502401-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/328d9cf788c9/fchem-12-1502401-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/97f1ac9a16e9/fchem-12-1502401-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/fae8e7da2b54/fchem-12-1502401-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/c53d08254777/fchem-12-1502401-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/7b355e2fa79b/fchem-12-1502401-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/e0e99d4a80bc/fchem-12-1502401-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/1ee3443e35d8/fchem-12-1502401-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/62d4cd584a0f/fchem-12-1502401-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/3d2c4392c89b/fchem-12-1502401-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/601296a2562a/fchem-12-1502401-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/eaf0d9f9aceb/fchem-12-1502401-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/7c3f39f40926/fchem-12-1502401-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/66d39975f82b/fchem-12-1502401-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/676fae0bb3ee/fchem-12-1502401-g022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/80a9a38d95ac/fchem-12-1502401-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/175a54e4804c/fchem-12-1502401-g024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/b04e460c50ef/fchem-12-1502401-g025.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/43c46b887f23/fchem-12-1502401-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/678b6e61c376/fchem-12-1502401-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/42cd25ad68b7/fchem-12-1502401-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/1a91cef8a6be/fchem-12-1502401-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/f2ac3b38661d/fchem-12-1502401-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/68811d3a0751/fchem-12-1502401-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/7a0aac6dc988/fchem-12-1502401-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/a74a786af245/fchem-12-1502401-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/328d9cf788c9/fchem-12-1502401-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/97f1ac9a16e9/fchem-12-1502401-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/fae8e7da2b54/fchem-12-1502401-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/c53d08254777/fchem-12-1502401-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/7b355e2fa79b/fchem-12-1502401-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/e0e99d4a80bc/fchem-12-1502401-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/1ee3443e35d8/fchem-12-1502401-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/62d4cd584a0f/fchem-12-1502401-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/3d2c4392c89b/fchem-12-1502401-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/601296a2562a/fchem-12-1502401-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/eaf0d9f9aceb/fchem-12-1502401-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/7c3f39f40926/fchem-12-1502401-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/66d39975f82b/fchem-12-1502401-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/676fae0bb3ee/fchem-12-1502401-g022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/80a9a38d95ac/fchem-12-1502401-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/175a54e4804c/fchem-12-1502401-g024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5498/11688193/b04e460c50ef/fchem-12-1502401-g025.jpg

相似文献

1
Covalent integration of polymers and porous organic frameworks.聚合物与多孔有机框架的共价整合。
Front Chem. 2024 Dec 18;12:1502401. doi: 10.3389/fchem.2024.1502401. eCollection 2024.
2
[Synthesis of porous organic framework materials based on deep eutectic solvents and their application in solid-phase extraction].基于低共熔溶剂的多孔有机骨架材料的合成及其在固相萃取中的应用
Se Pu. 2023 Oct;41(10):901-910. doi: 10.3724/SP.J.1123.2023.08025.
3
Progress in Hybridization of Covalent Organic Frameworks and Metal-Organic Frameworks.共价有机框架和金属有机框架的杂交进展。
Small. 2022 Sep;18(38):e2202928. doi: 10.1002/smll.202202928. Epub 2022 Aug 19.
4
[Preparation and application of chromatographic stationary phase based on two-dimensional materials].基于二维材料的色谱固定相的制备与应用
Se Pu. 2024 Jun;42(6):524-532. doi: 10.3724/SP.J.1123.2024.01022.
5
Covalent Metal-Organic Frameworks: Fusion of Covalent Organic Frameworks and Metal-Organic Frameworks.共价金属有机框架：共价有机框架与金属有机框架的融合
Acc Chem Res. 2025 Mar 4;58(5):746-761. doi: 10.1021/acs.accounts.4c00774. Epub 2025 Feb 21.
6
Two-Dimensional Heteropore Covalent Organic Frameworks: From Construction to Functions.二维异质孔共价有机框架：从构建到功能
Acc Chem Res. 2025 Apr 15;58(8):1192-1209. doi: 10.1021/acs.accounts.4c00799. Epub 2025 Mar 11.
7
Integration of Enzyme and Covalent Organic Frameworks: From Rational Design to Applications.酶与共价有机框架的整合：从合理设计到应用。
Acc Chem Res. 2024 Jan 2;57(1):93-105. doi: 10.1021/acs.accounts.3c00565. Epub 2023 Dec 17.
8
High-performance removal of radionuclides by porous organic frameworks from the aquatic environment: A review.多孔有机骨架在水环境污染治理中的应用：放射性核素的高效去除。
J Environ Radioact. 2021 Nov;238-239:106710. doi: 10.1016/j.jenvrad.2021.106710. Epub 2021 Sep 1.
9
[Research progress on preparation and applications of covalent organic framework-based chromatographic stationary phases].基于共价有机框架的色谱固定相的制备及应用研究进展
Se Pu. 2023 Oct;41(10):843-852. doi: 10.3724/SP.J.1123.2023.04021.
10
Nonporous Adaptive Crystals of Pillararenes.柱芳烃的无孔自适应晶体
Acc Chem Res. 2018 Sep 18;51(9):2064-2072. doi: 10.1021/acs.accounts.8b00255. Epub 2018 Jul 16.

本文引用的文献

1
From Data to Discovery: Recent Trends of Machine Learning in Metal-Organic Frameworks.从数据到发现：金属有机框架中机器学习的最新趋势
JACS Au. 2024 Sep 12;4(10):3727-3743. doi: 10.1021/jacsau.4c00618. eCollection 2024 Oct 28.
2
Construction of Porous Aromatic Frameworks with Specifically Designed Motifs for Charge Storage and Transport.用于电荷存储与传输的具有特定设计结构单元的多孔芳香框架的构建。
Acc Chem Res. 2024 Aug 6;57(15):2130-2143. doi: 10.1021/acs.accounts.4c00258. Epub 2024 Jul 23.
3
The Open DAC 2023 Dataset and Challenges for Sorbent Discovery in Direct Air Capture.
2023年开放式直接空气捕获吸附剂发现数据集及挑战
ACS Cent Sci. 2024 May 1;10(5):923-941. doi: 10.1021/acscentsci.3c01629. eCollection 2024 May 22.
4
Benchmark Investigation of SCC-DFTB against Standard and Hybrid DFT to Model Electronic Properties in Two-Dimensional MOFs for Thermoelectric Applications.用于热电应用的二维金属有机框架中电子性质建模的SCC-DFTB与标准和杂化密度泛函理论的基准研究。
J Chem Theory Comput. 2024 May 14;20(9):3976-3992. doi: 10.1021/acs.jctc.3c01405. Epub 2024 May 6.
5
The propensity for covalent organic frameworks to template polymer entanglement.共价有机框架促成聚合物缠结的倾向。
Science. 2024 Mar 22;383(6689):1337-1343. doi: 10.1126/science.adf2573. Epub 2024 Mar 21.
6
Effect of interlayer slipping on the geometric, thermal and adsorption properties of 2D covalent organic frameworks: a comprehensive review based on computational modelling studies.层间滑移对二维共价有机框架的几何、热学和吸附性能的影响：基于计算建模研究的综合综述
Phys Chem Chem Phys. 2024 Mar 13;26(11):8577-8603. doi: 10.1039/d4cp00094c.
7
Construction of MOFs@COFs composite material as stationary phase for efficient separation of diverse organic compounds.构建金属有机框架@共价有机框架复合材料作为固定相用于高效分离多种有机化合物。
Anal Chim Acta. 2024 Feb 1;1288:342160. doi: 10.1016/j.aca.2023.342160. Epub 2023 Dec 20.
8
Recent advances in the utilization of covalent organic frameworks (COFs) as electrode materials for supercapacitors.共价有机框架（COFs）作为超级电容器电极材料应用的最新进展。
Chem Sci. 2023 Nov 7;14(47):13601-13628. doi: 10.1039/d3sc04571d. eCollection 2023 Dec 6.
9
Ultra-fast supercritically solvothermal polymerization for large single-crystalline covalent organic frameworks.用于大型单晶共价有机框架的超快速超临界溶剂热聚合
Nat Protoc. 2024 Feb;19(2):340-373. doi: 10.1038/s41596-023-00915-7. Epub 2023 Nov 24.
10
Development of scalable and generalizable machine learned force field for polymers.用于聚合物的可扩展且通用的机器学习力场的开发。
Sci Rep. 2023 Oct 11;13(1):17251. doi: 10.1038/s41598-023-43804-5.