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用于功能性高性能空气过滤应用的藻酸盐/明胶共混纤维

Alginate/gelatin blend fibers for functional high-performance air filtration applications.

作者信息

Ahmetoglu Ubey, Gungor Melike, Kilic Ali

机构信息

Department of Nanoscience and Nanoengineering, Istanbul Technical University, Istanbul, Turkey.

Department of Textile Engineering, Istanbul Technical University, Istanbul, Turkey.

出版信息

Int J Biol Macromol. 2025 Mar;294:139389. doi: 10.1016/j.ijbiomac.2024.139389. Epub 2024 Dec 31.

Abstract

Currently, the primary composition of fibrous filter materials predominantly relies on synthetic polymers derived from petroleum. The utilization of these polymers, as well as their production process, has a negative impact on the environment. Consequently, the adoption of air filter media fabricated from natural fibers would yield significant environmental benefits. Nowadays not only particle and odour capture performance but also ensuring a high energy efficiency and flame retardant properties in air filters is of utmost importance for automotive and HVAC filters. In this study, for the production of biodegradable and flame retardant air filters with a high quality factor, free standing gelatin/sodium alginate blend fibers were successfully produced via centrifugal spinning. The water-soluble mats were stabilized by physical methods using both thermal and ionic crosslinking. The CGCA (Crosslinked-Gelatin/Calcium Alginate) mat exhibited exceptional filtration performance for PM0.3 particles, achieving a 94.2 % efficiency rating at a pressure drop of 135 Pa. Moreover, blending of biopolymers and subsequent calcination provided V0 level flame retardancy according to UL94 standard. The preliminary biodegradation studies showed that proposed nanofibrous filters were completely degraded in soil in 7 days.

摘要

目前,纤维过滤材料的主要成分主要依赖于源自石油的合成聚合物。这些聚合物的使用及其生产过程对环境有负面影响。因此,采用由天然纤维制成的空气过滤介质将产生显著的环境效益。如今,对于汽车和暖通空调过滤器而言,空气过滤器不仅要具备颗粒和气味捕获性能,还要确保高能效和阻燃性能。在本研究中,为了生产具有高品质因数的可生物降解且阻燃的空气过滤器,通过离心纺丝成功制备了独立的明胶/海藻酸钠共混纤维。水溶性垫通过热交联和离子交联的物理方法进行稳定化处理。CGCA(交联明胶/海藻酸钙)垫对PM0.3颗粒表现出卓越的过滤性能,在135 Pa的压降下实现了94.2%的效率评级。此外,生物聚合物的共混以及随后的煅烧根据UL94标准提供了V0级阻燃性。初步的生物降解研究表明,所提出的纳米纤维过滤器在7天内在土壤中完全降解。

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