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用于空气过滤的聚丙烯腈 - 氧化镁纳米纤维静电纺丝参数的优化

Optimization of electrospinning parameters for polyacrylonitrile-MgO nanofibers applied in air filtration.

作者信息

Dehghan Somayeh Farhang, Golbabaei Farideh, Maddah Bozorgmehr, Latifi Masoud, Pezeshk Hamid, Hasanzadeh Mahdi, Akbar-Khanzadeh Farhang

机构信息

a Department of Occupational Health , School of Public Health, Tehran University of Medical Sciences , Tehran , Iran.

b Department of Chemistry , Imam Hossein University , Tehran , Iran.

出版信息

J Air Waste Manag Assoc. 2016 Sep;66(9):912-21. doi: 10.1080/10962247.2016.1162228.

Abstract

UNLABELLED

The present study aimed to optimize the electrospinning parameters for polyacrylonitrile (PAN) nanofibers containing MgO nanoparticle to obtain the appropriate fiber diameter and mat porosity to be applied in air filtration. Optimization of applied voltage, solution concentration, and spinning distance was performed using response surface methodology. In total, 15 trials were done according to the prepared study design. Fiber diameter and porosity were measured using scanning electron microscopic (SEM) image analysis. For air filtration testing, the nanofiber mat was produced based on the suggested optimum conditions for electrospinning. According to the results, the lower solution concentration favored the thinner fiber. The larger diameter gave a higher porosity. At a given spinning distance, there was a negative correlation between fiber diameter and applied voltage. Moreover, there were curvilinear relationships between porosity and both spinning distance and applied voltage at any concentration. It was also concluded that the developed filter medium could be comparable to the high-efficiency particulate air (HEPA) filter in terms of collection efficiency and pressure drop. The empirical models presented in this study can provide an orientation to the subsequent experiments to form uniform and continuous nanofibers for future application in air purification.

IMPLICATIONS

High-efficiency filtration is becoming more important, due to decreasing trends air quality. Effective filter media are increasingly needed in industries applying clean-air technologies, and the necessity for developing the high-performance air filters has been more and more felt. Nanofibrous filter media that are mostly fabricated via electrospinning technique have attracted considerable attention in the last decade. The present study aimed to develop the electrospun PAN-containing MgO nanoparticle (using the special functionalities such as absorption and adsorption characteristics, antibacterial functionality, and as a pore-forming agent) filter medium through experimental investigations for application in high-performance air filters.

摘要

未标注

本研究旨在优化含氧化镁纳米颗粒的聚丙烯腈(PAN)纳米纤维的静电纺丝参数,以获得适用于空气过滤的合适纤维直径和毡孔隙率。采用响应面法对施加电压、溶液浓度和纺丝距离进行了优化。根据所制备的研究设计,总共进行了15次试验。使用扫描电子显微镜(SEM)图像分析测量纤维直径和孔隙率。为了进行空气过滤测试,根据建议的静电纺丝最佳条件制备了纳米纤维毡。结果表明,较低的溶液浓度有利于形成更细的纤维。直径越大,孔隙率越高。在给定的纺丝距离下,纤维直径与施加电压之间呈负相关。此外,在任何浓度下,孔隙率与纺丝距离和施加电压之间均存在曲线关系。研究还得出结论,所开发的过滤介质在收集效率和压降方面可与高效空气过滤器(HEPA)相媲美。本研究中提出的经验模型可为后续实验提供指导,以形成均匀连续的纳米纤维,用于未来的空气净化应用。

启示

由于空气质量呈下降趋势,高效过滤变得越来越重要。在应用清洁空气技术的行业中,越来越需要有效的过滤介质,并且人们越来越感受到开发高性能空气过滤器的必要性。在过去十年中,主要通过静电纺丝技术制造的纳米纤维过滤介质受到了广泛关注。本研究旨在通过实验研究开发含氧化镁纳米颗粒的静电纺PAN过滤介质(利用其吸收、吸附特性、抗菌功能以及作为造孔剂等特殊功能),以应用于高性能空气过滤器。

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