Construction of carbon dot-embedded fluorescent hydrogels based on oxidized gum arabic-gelatin Schiff base for Cr(VI) detection applications.

In this study, a novel nitrogen-doped carbon quantum dot/oxidized gum arabic-gelatin-based fluorescent probe (NAH) was prepared using gelatin (GL) and gum arabic (AG) biomolecules. The primary network structure of this hydrogel consisted of polyacrylamide (PAM), while a secondary network structure was constructed between oxidized gum arabic and gelatin through the reaction of the Schiff base, which significantly enhanced the mechanical properties, the stress and strain of NAH reached 266.47 KPa and 2175.75 %. Nitrogen-doped carbon dots (NCDs) with yellow fluorescence emission properties were synthesized by hydrothermal method using salicylic acid as the carbon source and o-phenylenediamine as the nitrogen source. The fluorescent sensor obtained by compounding NCDs with hydrogel was able to selectively detect Cr(VI). The linear range of its detection was 0-90 μM, and the detection limit was 0.19 μM. The maximum theoretical adsorption capacity of the NAH hydrogel was 169.4 mg/g, and its adsorption isotherm conformed to the Langmuir adsorption isotherm model, and the adsorption kinetics conformed to the quasi-secondary kinetic model. Compared with the NCDs solution, the NAH hydrogel showed superior comprehensive performance, especially in solving the problem of recovery of NCDs. Meanwhile, this hydrogel provides an effective insight into the efficient detection and adsorption of environmental pollutants.