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模拟深层放射性废物处置条件下铜的微生物腐蚀

Microbial Corrosion of Copper Under Conditions Simulating Deep Radioactive Waste Disposal.

作者信息

Abramova Elena, Shapagina Natalia, Artemiev Grigoriy, Safonov Alexey

机构信息

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, Russia.

出版信息

Biology (Basel). 2024 Dec 23;13(12):1086. doi: 10.3390/biology13121086.

Abstract

This paper presents the results of microbial corrosion tests on M0-grade copper under conditions simulating a geological repository for radioactive waste at the Yeniseisky site (Krasnoyarsk Krai, Russia). The work used a microbial community sampled from a depth of 450 m and stimulated with glucose, hydrogen and sulfate under anaerobic conditions. It was shown that the maximum corrosion rate, reaching 9.8 µm/y, was achieved with the addition of sulfate (1 g/L) with the participation of microorganisms from the families , and . It was noted that the most important factor leading to copper corrosion was the accumulation of hydrogen sulfide during the activation of sulfate-reducing microorganisms of the genera , and During the development of the microbial community under these conditions, the content of copper can have a significant toxic effect at a concentration of more than 250 mg/L.

摘要

本文介绍了在模拟俄罗斯克拉斯诺亚尔斯克边疆区叶尼塞斯基场址放射性废物地质处置库的条件下,对M0级铜进行微生物腐蚀试验的结果。该研究使用了从450米深处采集的微生物群落,并在厌氧条件下用葡萄糖、氢气和硫酸盐进行刺激。结果表明,在添加硫酸盐(1克/升)且有 科、 科和 科微生物参与的情况下,最大腐蚀速率达到9.8微米/年。研究指出,导致铜腐蚀的最重要因素是在 属、 属和 属硫酸盐还原微生物活化过程中硫化氢的积累。在这些条件下微生物群落发展过程中,铜含量在超过250毫克/升时会产生显著的毒性作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b9db/11673040/65eece51d514/biology-13-01086-g001.jpg

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