Dragan Mirela
National Research and Development Institute for Non-Ferrous and Rare Metals-IMNR, 102 Biruintei Blvd., 077145 Pantelimon, Ilfov, Romania.
Materials (Basel). 2024 Dec 13;17(24):6113. doi: 10.3390/ma17246113.
Solid oxide fuel cells (SOFCs) and solid oxide electrolyzer cells (SOECs) represent a promising clean energy solution. In the case of SOFCs, they offer efficiency and minimal to zero CO emissions when used to convert chemical energy into electricity. When SOFC systems are operated in regenerative mode for water electrolysis, the SOFCs become solid oxide electrolyzer cells (SOECs). The problem with these systems is the supply and availability of raw materials for SOFC and SOEC components. This raises significant economic challenges and has an impact on the price and scalability of these technologies. Recycling the materials that make up these systems can alleviate these economic challenges by reducing dependence on the supply of raw materials and reducing overall costs. From this point of view, this work is a perspective analysis and examines the current research on the recycling of SOFC and SOEC materials, highlighting the potential paths towards a circular economy. The existing literature on different approaches to recycling the key materials for components of SOFCs and SOECs is important. Mechanical separation techniques to isolate these components, along with potential strategies like chemical leaching or hydrometallurgical and material characterization, to ensure the quality of recycled materials for reuse in new SOFCs and SOECs are important as well. By evaluating the efficiency of various methods and the quality of recovered materials, this study aims to provide valuable insights for advancing sustainable and economically viable SOFC and SOEC technologies within a net-zero economic framework.
固体氧化物燃料电池(SOFC)和固体氧化物电解槽(SOEC)是一种很有前景的清洁能源解决方案。对于SOFC而言,当用于将化学能转化为电能时,它们具有高效且几乎零碳排放的特点。当SOFC系统以再生模式运行进行水电解时,SOFC就变成了固体氧化物电解槽(SOEC)。这些系统存在的问题是SOFC和SOEC组件原材料的供应和可得性。这带来了重大的经济挑战,并对这些技术的价格和可扩展性产生影响。回收构成这些系统的材料可以通过减少对原材料供应的依赖和降低总体成本来缓解这些经济挑战。从这个角度来看,这项工作是一项前瞻性分析,考察了目前关于SOFC和SOEC材料回收利用的研究,突出了通向循环经济的潜在途径。关于回收SOFC和SOEC组件关键材料的不同方法的现有文献很重要。用于分离这些组件的机械分离技术,以及诸如化学浸出或湿法冶金和材料表征等潜在策略,对于确保回收材料的质量以便在新的SOFC和SOEC中重复使用也很重要。通过评估各种方法的效率和回收材料的质量,本研究旨在为在净零经济框架内推进可持续且经济可行的SOFC和SOEC技术提供有价值的见解。