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新型聚氨酯快速固化高分子材料的性能研究

On the Properties of New Polyurethane Fast-Curing Polymer Materials.

作者信息

Liu Huachao, Deng Jiajun, Li Shuchen, Liu Richeng, Yu Liyuan, Ma Linjian

机构信息

State Key Laboratory of Explosion & Impact and Disaster Prevention & Mitigation, Army Engineering University of PLA, Nanjing 210007, China.

School of Mechanics and Civil Engineering, China University of Mining and Technology, Xuzhou 221116, China.

出版信息

Materials (Basel). 2024 Dec 20;17(24):6231. doi: 10.3390/ma17246231.

DOI:10.3390/ma17246231
PMID:39769831
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11676238/
Abstract

A sequences of unconfined compressive strength tests and flexural tests were conducted in this study to evaluate the curing performance of a new type of polyurethane sand fast-curing polymer material. The mechanical properties of the material were investigated under different curing temperatures (-10 °C to 60 °C), particle sizes (10-15 mesh, 60-80 mesh, 100-120 mesh, and 325 mesh), and material proportions (20% to 60%). Additionally, SEM analysis was employed to further reveal the reinforcement mechanism. The results demonstrated that the developed polyurethane polymer material exhibited superior curing properties and applicability across a wide temperature range of -10 °C to 60 °C. Both the compressive strength and flexural strength of the solidified sand increased with the increase in solidification temperature, resulting in improved curing effects. This material exhibited the best curing properties when using sand within the 100-120 mesh range. As the particle size decreased under the remaining specifications, there was a reduction in specimen strain and an increase in strength, while still maintaining favorable ductility. The optimal proportion for polyurethane material was 40%. Moreover, the nonlinear mathematical relationships between the strength and multiple influencing factors were established through multivariate regression analysis. The sand consolidation specimens exhibited X-shaped conjugate shear failure, which tended to occur at the weak interface between the sand and material. Lastly, Pearson's correlation analysis revealed a strong positive correlation between temperature and material content with strength.

摘要

本研究进行了一系列无侧限抗压强度试验和弯曲试验,以评估一种新型聚氨酯砂快速固化聚合物材料的固化性能。在不同固化温度(-10℃至60℃)、粒径(10 - 15目、60 - 80目、100 - 120目和325目)和材料比例(20%至60%)下,对该材料的力学性能进行了研究。此外,采用扫描电子显微镜(SEM)分析进一步揭示增强机理。结果表明,所开发的聚氨酯聚合物材料在-10℃至60℃的宽温度范围内表现出优异的固化性能和适用性。固化砂的抗压强度和弯曲强度均随固化温度的升高而增加,固化效果得到改善。当使用100 - 120目范围内的砂时,该材料表现出最佳的固化性能。在其余规格下,随着粒径减小,试样应变减小,强度增加,同时仍保持良好的延展性。聚氨酯材料的最佳比例为40%。此外,通过多元回归分析建立了强度与多个影响因素之间的非线性数学关系。砂固结试样表现出X形共轭剪切破坏,这种破坏倾向于发生在砂与材料之间的薄弱界面处。最后,Pearson相关分析表明温度和材料含量与强度之间存在强正相关。

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本文引用的文献

1
Unconfined Compressive Properties of Composite Sand Stabilized with Organic Polymers and Natural Fibers.有机聚合物和天然纤维稳定复合砂的无侧限抗压性能
Polymers (Basel). 2019 Sep 27;11(10):1576. doi: 10.3390/polym11101576.
2
Evaluation of Strength Properties of Sand Modified with Organic Polymers.有机聚合物改性砂的强度特性评估
Polymers (Basel). 2018 Mar 8;10(3):287. doi: 10.3390/polym10030287.
3
Effect of Sisal Fiber and Polyurethane Admixture on the Strength and Mechanical Behavior of Sand.剑麻纤维与聚氨酯外加剂对砂强度及力学性能的影响
Polymers (Basel). 2018 Oct 10;10(10):1121. doi: 10.3390/polym10101121.