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低渗透砂砾岩油藏不同类型表面活性剂强化自吸机理实验研究

Experimental Study on the Mechanism of Enhanced Imbibition with Different Types of Surfactants in Low-Permeability Glutenite Reservoirs.

作者信息

Qu Hongyan, Shi Jilong, Wu Mengyao, Zhou Fujian, Zhang Jun, Peng Yan, Yu Tianxi, Pan Zhejun

机构信息

National Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, China.

College of Carbon Neutral Energy, China University of Petroleum, Beijing 102249, China.

出版信息

Molecules. 2024 Dec 17;29(24):5953. doi: 10.3390/molecules29245953.

Abstract

Due to the complex physical properties of low-permeability glutenite reservoirs, the oil recovery rate with conventional development is low. Surfactants are effective additives for enhanced oil recovery (EOR) due to their good ability of wettability alteration and interfacial tension (IFT) reduction, but the reason why imbibition efficiencies vary with different types of surfactants and the mechanism of enhanced imbibition in the glutenite reservoirs is not clear. In this study, the imbibition efficiency and recovery of surfactants including the nonionic, anionic, and cationic surfactants as well as nanofluids were evaluated and compared with produced water (PW) using low-permeability glutenite core samples from the Lower Urho Formation in the Mahu oil field. Experiments of IFT, wettability, emulsification, and imbibition at high-temperature and high-pressure were conducted to reveal the underlying EOR mechanisms of different types of surfactants. The distribution and utilization of oil in different pores during the imbibition process were characterized by a combined method of mercury intrusion and nuclear magnetic resonance (NMR). The main controlling factors of surfactant-enhanced imbibition in glutenite reservoirs were clarified. The results demonstrate that the micropores and mesopores contribute most to imbibition recovery in low-permeability glutenite reservoirs. The anionic surfactant KPS exhibits a good capacity of reducing IFT, wettability alteration, and oil emulsification with the highest oil recovery of 49.02%, 8.49% higher than PW. The nonionic surfactant OP-10 performs well on oil emulsification and wetting modification with imbibition recovery of 48.11%. This study sheds light on the selection of suitable surfactants for enhanced imbibition in low-permeability glutenite reservoirs and improves the understanding of oil production through enhanced imbibition.

摘要

由于低渗透砂砾岩油藏具有复杂的物理性质,常规开发方式的原油采收率较低。表面活性剂因其良好的润湿性改变能力和降低界面张力(IFT)的能力,是提高采收率(EOR)的有效添加剂,但不同类型表面活性剂的自吸效率为何不同以及砂砾岩油藏中自吸强化机理尚不清楚。在本研究中,使用玛湖油田下乌尔禾组低渗透砂砾岩岩心样品,对包括非离子、阴离子和阳离子表面活性剂以及纳米流体在内的表面活性剂的自吸效率和采收率进行了评估,并与采出水(PW)进行了比较。进行了高温高压下的IFT、润湿性、乳化和自吸实验,以揭示不同类型表面活性剂潜在的提高采收率机理。通过压汞法和核磁共振(NMR)相结合的方法表征了自吸过程中不同孔隙内油的分布和利用情况。明确了砂砾岩油藏中表面活性剂强化自吸的主要控制因素。结果表明微孔和中孔对低渗透砂砾岩油藏的自吸采收率贡献最大。阴离子表面活性剂KPS具有良好的降低IFT、改变润湿性和乳化油的能力,最高采收率为49.02%,比采出水高8.49%。非离子表面活性剂OP-10在油乳化和润湿性改性方面表现良好,自吸采收率为48.11%。本研究为低渗透砂砾岩油藏强化自吸选择合适的表面活性剂提供了依据,并增进了对通过强化自吸提高原油产量的理解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1cc9/11679662/de7f56e5a8a1/molecules-29-05953-g001.jpg

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