Sorption of Platinum and Palladium on Polyethylene Microplastics in Natural Water.

In this work, for the first time, the sorption behaviour of platinum and palladium on polyethylene microplastics (PE-MP) was studied. To simulate natural conditions, part of PE-MP was subjected to the ageing process in lake water under the influence of solar radiation. The original and aged PE-MP was characterised using elemental analysis, FT-IR, SEM-EDX, and nitrogen porosimetry methods. The studies on Pt and Pd sorption on PE-MP were carried out in batch mode in natural lake water at pH 7.6. It was found that the ageing process led to the degradation of the surface of the PE-MP and the formation of a biofilm. The sorption process of Pt and Pd on PE-MP particles proceeds according to pseudo-second-order kinetics. A good fit of the experimental data to the Freundlich and Langmuir isotherm model indicates the mixed nature of Pt and Pd sorption on PE-MP. It was clearly indicated that Pt and Pd sorption from natural waters can occur on the surface of inert polyethylene particles, which can lead to the preconcentration of these elements, even from waters with a very low content, and transferring them over longer distances. This poses a threat to the health of living organisms and humans.