Xia Chunqiu, Cao Xuanhao, Wen Jiuran, Li Jun, Dai Li, Guan Bowen
School of Materials Science and Engineering, Chang'an University, Xi'an 710061, China.
Jiangxi Communications Investment Group Co., Ltd., Nanchang 330108, China.
Polymers (Basel). 2024 Dec 11;16(24):3462. doi: 10.3390/polym16243462.
In order to investigate the mechanism of mechanical performance enhancement and the curing mechanisms of acrylate emulsion (AE) in cement and magnesium slag (MS) composite-stabilized soil (AE-C-M), this study has conducted a comprehensive analysis of the compressive strength and microstructural characteristics of AE-C-M stabilized soil. The results show that the addition of AE significantly improves the compressive strength of the stabilized soil. When the AE content is 0.4%, the cement content is 3%, and the magnesium slag content is 3% (AE4-C3M3), the strength of the formula reaches 4.21 MPa, which meets the requirements of heavy traffic load conditions in the construction of high-speed or main road base layers. Some reactive groups on the polymer side chains (-COOH) engage in bridging with Ca and RCOO to form a chemically bonded interpenetrating network structure, thereby enabling the acrylate emulsion to enhance the water damage resistance of the specimens. The notable improvement in strength is attributed to the film-forming and solidifying actions of AE, the binding and filling effects of C-S-H gel, and the reinforcing effect of straw fibers. FT-IR and TG-DSC analysis reveals the presence of polar electrostatic interactions between AE and the soil matrix. AE enhances the bonding among soil particles and facilitates the attachment of C-S-H gel onto the surfaces of the straw fibers, thereby increasing the strength and toughness of the material. The application of MS in conjunction with straw fibers within polymer-modified stabilized soil serves to promote the recycling of waste materials, thereby providing an environmentally friendly solution for the engineering application of solid waste.
为了研究丙烯酸酯乳液(AE)在水泥和镁渣(MS)复合稳定土(AE-C-M)中增强力学性能的机理及固化机理,本研究对AE-C-M稳定土的抗压强度和微观结构特征进行了综合分析。结果表明,AE的添加显著提高了稳定土的抗压强度。当AE含量为0.4%、水泥含量为3%、镁渣含量为3%(AE4-C3M3)时,配方强度达到4.21MPa,满足高速或主干道基层施工中重交通荷载条件的要求。聚合物侧链上的一些反应基团(-COOH)与Ca和RCOO进行桥连,形成化学键合的互穿网络结构,从而使丙烯酸酯乳液提高了试件的抗水损害性能。强度的显著提高归因于AE的成膜和固化作用、C-S-H凝胶的粘结和填充作用以及秸秆纤维的增强作用。FT-IR和TG-DSC分析揭示了AE与土壤基质之间存在极性静电相互作用。AE增强了土壤颗粒之间的粘结力,并促进了C-S-H凝胶附着在秸秆纤维表面,从而提高了材料的强度和韧性。MS与秸秆纤维在聚合物改性稳定土中的联合应用有助于促进废料的回收利用,从而为固体废物的工程应用提供了一种环保解决方案。