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马尾松和杉木木粉增强高密度聚乙烯复合材料的物理、力学及蠕变性能表征研究

Study on the Characterization of Physical, Mechanical, and Creep Properties of Masson Pine and Chinese Fir Wood Flour-Reinforced High-Density Polyethylene Composites.

作者信息

Xu Hailong, Hua Xueshan, Cao Yan, Li Lifen, Liu Baoyu, Yang Xiaohui, Gao Hua

机构信息

Special and Key Laboratory for Development and Utilization of Guizhou Superior Bio-Based Materials, Guizhou Minzu University, Guiyang 550025, China.

Engineering Research Center of Green and Low-Carbon Technology for Plastic Application, Guizhou Minzu University, Guiyang 550025, China.

出版信息

Polymers (Basel). 2024 Dec 17;16(24):3507. doi: 10.3390/polym16243507.

Abstract

Improving the physical, mechanical, and creep properties of wood fiber-reinforced polymer composites is crucial for broadening their application prospect. In this research, seven types of high-density polyethylene (HDPE) composites reinforced with different mass ratios of Masson pine ( Lamb.) and Chinese fir [ (Lamb.) Hook.] were prepared by a two-step extrusion molding method. The mass ratios of the two fibers were 60:0, 50:10, 40:20, 30:30, 20:40, 10:50, and 0:60, respectively. The surface color, density, dimension stability, bending, tensile, impact properties, dynamic mechanical properties, and 24 h creep properties at a 10% stress level of the seven composites were investigated. Additionally, the Rule of Mixtures (ROM), the Inverse Rule of Mixtures (IROM), the Hirsch models, and the improved model were employed to simulate the mechanical properties, while the Findley index model, the two-parameter index model, and the modified ExpAssoc model were employed to simulate the creep performance of the composites. This study revealed that as the proportion of Chinese fir wood flour increased, the mechanical properties of the composites gradually improved, the storage modulus showed an increasing trend, while the loss modulus decreased, and the overall creep strain of the composites increased. Among the various models, the modified model simulated the mechanical properties of the composites the best, while the modified ExpAssoc model simulated the creep behavior most effectively.

摘要

改善木纤维增强聚合物复合材料的物理、机械和蠕变性能对于拓宽其应用前景至关重要。在本研究中,采用两步挤出成型法制备了七种不同质量比的马尾松(Lamb.)和杉木[(Lamb.)Hook.]增强的高密度聚乙烯(HDPE)复合材料。两种纤维的质量比分别为60:0、50:10、40:20、30:30、20:40、10:50和0:60。研究了这七种复合材料的表面颜色、密度、尺寸稳定性、弯曲、拉伸、冲击性能、动态力学性能以及在10%应力水平下的24小时蠕变性能。此外,采用混合法则(ROM)、反混合法则(IROM)、赫希模型和改进模型来模拟力学性能,同时采用芬德利指数模型、双参数指数模型和修正的ExpAssoc模型来模拟复合材料的蠕变性能。本研究表明,随着杉木粉比例的增加,复合材料的力学性能逐渐提高,储能模量呈上升趋势,而损耗模量下降,复合材料的整体蠕变应变增加。在各种模型中,改进模型对复合材料力学性能的模拟效果最佳,而修正的ExpAssoc模型对蠕变行为的模拟最有效。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2459/11679436/03a6bb97f94f/polymers-16-03507-g001.jpg

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