Moheb Mona, El-Wakil Ahmad M, Awad Fathi S
Chemistry Department, Faculty of Science, Mansoura University Mansoura 35516 Egypt
Chemistry Department, Faculty of Science, New Mansoura University New Mansoura 35712 Egypt.
RSC Adv. 2025 Jan 8;15(1):674-687. doi: 10.1039/d4ra07957d. eCollection 2025 Jan 2.
In this study, stems and leaves of the papaya plant were employed to prepare a high-quality porous adsorbent carbonization and chemical activation using phosphoric acid. This adsorbent demonstrates superior adsorption capabilities for the efficient removal of hazardous alizarin red s (ARS) and methylene blue (MB) dyes. Thus, it contributes to waste reduction and promotes sustainable practices in environmental remediation, aligning with global efforts to develop sustainable materials that address water pollution while supporting circular economy principles. The structural properties of the activated carbon were characterized through various techniques, including BET surface area, FTIR, SEM, XPS, zeta potential measurements, and determination of the zero-point charge. The characterization results confirmed the preparation of highly porous activated carbon from papaya stems with a high surface area of 1053.52 m g. The batch experiments revealed that the maximum adsorption capacities for the stem-activated carbon (SAC) were 931 mg g for ARS and 990 mg g for MB. For the leave-activated carbon (LAC), the capacities were 410 mg g for ARS and 642 mg g for MB. SAC exhibited 100% removal of MB or ARS with concentrations lower than 150 ppm in 15 min. The data fitted well with the Langmuir model and pseudo-second-order model. Moreover, the reusability revealed that the SAC can be reused over 5 cycles without significant change in the removal efficiency. Overall, SAC and LAC derived from papaya plants exhibited excellent dye adsorption performance, suggesting potential for large-scale applications.
在本研究中,番木瓜植物的茎和叶被用于制备一种高质量的多孔吸附剂,通过磷酸进行碳化和化学活化。这种吸附剂对高效去除有害的茜素红S(ARS)和亚甲基蓝(MB)染料具有卓越的吸附能力。因此,它有助于减少废物,并在环境修复中促进可持续实践,符合全球开发可持续材料以解决水污染问题并支持循环经济原则的努力。通过包括BET表面积、傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、zeta电位测量以及零电荷点测定等各种技术对活性炭的结构性质进行了表征。表征结果证实了从番木瓜茎制备出了具有1053.52 m²/g高表面积的高度多孔活性炭。批量实验表明,茎活性炭(SAC)对ARS的最大吸附容量为931 mg/g,对MB的最大吸附容量为990 mg/g。对于叶活性炭(LAC),对ARS的容量为410 mg/g,对MB的容量为642 mg/g。SAC在15分钟内对浓度低于150 ppm的MB或ARS的去除率达到100%。数据与朗缪尔模型和伪二级模型拟合良好。此外,可重复使用性表明SAC可以重复使用超过5个循环,而去除效率没有显著变化。总体而言,源自番木瓜植物的SAC和LAC表现出优异的染料吸附性能,表明具有大规模应用的潜力。