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用于生物柴油合成及硫化物氧化的含磺酸基团的磁性纳米固体酸催化剂

Magnetic nano-sized solid acid catalyst bearing sulfonic acid groups for biodiesel synthesis and oxidation of sulfides.

作者信息

Singh Durgesh, Singh Kamini, Jadeja Yashwantsinh, Menon Soumya V, Singh Priyanka, Ibrahim Safaa Mohammed, Singh Manmeet, Abosaoda Munther Kadhim, Al Reshaidan Salwa Bader, El-Meligy Mohammed A

机构信息

Department of Chemistry, School of Chemical Sciences and Technology, Dr. Harisingh Gour Vishwavidyalaya (A Central University), Sagar, 470003, India.

Department of Chemistry, Deen Dayal Upadhyay Gorakhpur University, Gorakhpur, 273009, India.

出版信息

Sci Rep. 2025 Jan 9;15(1):1397. doi: 10.1038/s41598-024-84494-x.

Abstract

In this study, the AlFeO@n-Pr@Et-SOH heterogeneous catalyst was successfully synthesized and utilized to produce biodiesel from oleic acid through an esterification process and to oxidize sulfides. To examine the physicochemical characteristics of the AlFeO@n-Pr@Et-SOH nanomaterial, a variety of advanced techniques were employed, including Fourier Transform infrared spectroscopy (FT-IR), Field emission scanning electron microscopy (FE-SEM), Energy dispersive X-ray spectroscopy (EDX), Vibrating sample magnetometer (VSM), Elemental Mapping, Transmission electron microscopy (TEM), Inductively coupled plasma (ICP), and X-ray diffraction (XRD). The AlFeO@n-Pr@Et-SOH materials demonstrated excellent performance in both the esterification of oleic acid and the oxidation of sulfides. Moreover, the catalyst can be easily recovered and reused multiple times without a significant reduction in its effectiveness.

摘要

在本研究中,成功合成了AlFeO@n-Pr@Et-SOH多相催化剂,并将其用于通过酯化过程由油酸生产生物柴油以及氧化硫化物。为了研究AlFeO@n-Pr@Et-SOH纳米材料的物理化学特性,采用了多种先进技术,包括傅里叶变换红外光谱(FT-IR)、场发射扫描电子显微镜(FE-SEM)、能量色散X射线光谱(EDX)、振动样品磁强计(VSM)、元素映射、透射电子显微镜(TEM)、电感耦合等离子体(ICP)和X射线衍射(XRD)。AlFeO@n-Pr@Et-SOH材料在油酸酯化和硫化物氧化方面均表现出优异的性能。此外,该催化剂易于回收并可多次重复使用,而其有效性不会显著降低。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8ef/11718112/24229642dcd4/41598_2024_84494_Fig1_HTML.jpg

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