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稀土预处理提高活性染料雅格素海军蓝在香蕉纤维织物上的性能。

Rare-Earth Pretreatment Improves Performance of Reactive Dye Argazol Navy Blue on Banana-Fiber Fabric.

作者信息

Du Ao, Zheng Yongjie, Jiang Wenqi, Liu Jie

机构信息

College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, China.

Engineering Research Center for Hemp and Product in Cold Region of Ministry of Education, Qiqihar University, Qiqihar 161006, China.

出版信息

Molecules. 2025 Jan 4;30(1):176. doi: 10.3390/molecules30010176.

Abstract

At present, the use of conventional reactive dyes on banana-fiber fabric leads to the problem of excessive salt consumption, which is not conducive to environmental protection. In this experimental study, rare-earth-pretreated banana-fiber fabric was dyed with the reactive dye Argazol Navy Blue. The rare-earth pretreatment was carried out to reduce the level of salt consumption, improve dyeing and fixation rates, and reduce the treatment burden of printing and dyeing wastewater. Dye uptake and fixation rates were used as indicators. Single-change factors were assessed by analyzing different amounts of rare earth, sodium carbonate, and sodium chloride, as well as different fixation times and temperatures, so that the effects of the dye additive on the dyed banana-fiber fabric could be investigated. After appropriate ranges were determined for single-change factors, an orthogonal experiment was carried out to establish optimal parameters for the process of dyeing rare-earth-pretreated banana-fiber fabric with Argazol Navy Blue. These parameters were as follows: the required amount of rare earth was 0.40% (o.w.f.); the amount of dye was 2% (o.w.f.); the amount of sodium chloride was 15 g/L; the amount of sodium carbonate was 9 g/L; the fixing temperature was 75 °C; and the fixing time was 45 min. These optimized process parameters were then used to dye the banana-fiber fabric as a whole. Our results showed that the dye uptake and fixation rates for rare-earth-pretreated banana-fiber fabric dyed with navy-blue dye reached 56.85% and 45.32%, respectively. Finally, the effect of rare-earth pretreatment on dyeing performance was analyzed using FT-IR, SEM, and EDS.

摘要

目前,在香蕉纤维织物上使用传统活性染料会导致耗盐量过大的问题,这不利于环境保护。在本实验研究中,用活性染料雅格素海军蓝对经稀土预处理的香蕉纤维织物进行染色。进行稀土预处理是为了降低耗盐量、提高染色和固色率,并减轻印染废水的处理负担。以染料上染率和固色率作为指标。通过分析不同用量的稀土、碳酸钠、氯化钠以及不同的固色时间和温度等单因素变化,来研究染料添加剂对染色香蕉纤维织物的影响。在确定单因素变化的合适范围后,进行正交试验以确定用雅格素海军蓝对经稀土预处理的香蕉纤维织物染色工艺的最佳参数。这些参数如下:稀土用量为0.40%(对织物质量);染料用量为2%(对织物质量);氯化钠用量为15 g/L;碳酸钠用量为9 g/L;固色温度为75℃;固色时间为45分钟。然后使用这些优化后的工艺参数对香蕉纤维织物整体进行染色。我们的结果表明,用海军蓝染料对经稀土预处理的香蕉纤维织物染色,其上染率和固色率分别达到56.85%和45.32%。最后,利用傅里叶变换红外光谱(FT-IR)、扫描电子显微镜(SEM)和能谱仪(EDS)分析了稀土预处理对染色性能的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a03/11722163/018e7e8de33a/molecules-30-00176-g001.jpg

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