Masa Abdulhakim, Jehsoh Nureeyah, Hayeemasae Nabil
Rubber Engineering Program, Department of Interdisciplinary Engineering, Faculty of Engineering, Prince of Songkla University, Songkhla 90110, Thailand.
Department of Rubber Technology and Polymer Science, Faculty of Science and Technology, Prince of Songkla University, Pattani Campus, Pattani 94000, Thailand.
Polymers (Basel). 2025 Jan 2;17(1):106. doi: 10.3390/polym17010106.
This study examined the feasibility of using natural rubber (NR) latex foam as a dye adsorbent and antibacterial foam. The dyes used in this experiment were Methylene Blue (MB) and Alizarin Yellow (AY). Foams with that optimum density were further evaluated for adsorption isotherm, kinetics, and thermodynamic data. The dye adsorption occurred in two steps: the initial and the stabilized stages where an increase in dye concentrations boosted the adsorption capacity. Based on the prediction, the maximum adsorptions of MB and AY from the solution were 3.15 and 10.31 mg/g, respectively. The Langmuir isotherm fits better with the adsorption of MB while AY is better matched by the Freundlich isotherm. Moreover, the adsorption behavior fits well with the pseudo-second-order model. MB took much longer to reach the stabilized stage, especially at high dye concentrations. The thermodynamic study revealed that physical adsorption accounted for most of the adsorption. Later, the foam after use as an adsorbent was further utilized as an antibacterial foam. Based on the qualitative and quantitative aspects, the results indicate that the dye-carrying foam could inhibit the growth of both Gram-positive and Gram-negative bacteria. It can be concluded that NR latex foam can be applied as a dye adsorbent and further utilized as an antibacterial foam.
本研究考察了使用天然橡胶(NR)乳胶泡沫作为染料吸附剂和抗菌泡沫的可行性。本实验中使用的染料为亚甲基蓝(MB)和茜素黄(AY)。对具有最佳密度的泡沫进一步评估其吸附等温线、动力学和热力学数据。染料吸附分两个阶段进行:初始阶段和稳定阶段,染料浓度的增加会提高吸附容量。根据预测,溶液中MB和AY的最大吸附量分别为3.15和10.31 mg/g。Langmuir等温线更适合MB的吸附,而AY更符合Freundlich等温线。此外,吸附行为与准二级模型拟合良好。MB达到稳定阶段所需的时间长得多,尤其是在高染料浓度下。热力学研究表明,物理吸附占吸附的大部分。后来,用作吸附剂后的泡沫进一步用作抗菌泡沫。基于定性和定量方面,结果表明载有染料的泡沫可以抑制革兰氏阳性菌和革兰氏阴性菌的生长。可以得出结论,NR乳胶泡沫可以用作染料吸附剂,并进一步用作抗菌泡沫。