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一种阻燃隔音复合功能密封胶的研制

Development of a Fire-Retardant and Sound-Insulating Composite Functional Sealant.

作者信息

Li Shiwen, Wang Mingyu, Tu Jinchun, Wang Bingrong, Wang Xiaohong, Zhang Kexi

机构信息

School of Materials Science and Engineering, Hainan University, Haikou 570228, China.

School of Chemistry and Chemical Engineering, Hainan University, Haikou 570228, China.

出版信息

Materials (Basel). 2024 Dec 27;18(1):62. doi: 10.3390/ma18010062.

Abstract

The use of traditional sealing materials in buildings poses a significant risk of fire and noise pollution. To address these issues, we propose a novel composite functional sealant designed to enhance fire safety and sound insulation. The sealant incorporates a unique four-component filler system consisting of carbon nanotubes (CNTs) decorated with layered double hydroxides (LDHs), ammonium dihydrogen phosphate (ADP), and artificial marble waste powder (AMWP), namely CLAA. The CNTs/LDHs framework provides structural support and enhances thermal stability, while the ADP layer acts as a protective barrier and releases non-combustible gases during combustion. AMWP particles contribute to sound insulation by creating impedance mismatches. The resulting composite functional sealant exhibits improved mechanical properties. In terms of flame retardancy, it boasts the lowest peak heat release rate (PHRR) of 224.83 kW/m and total smoke release (TSR) of 981.14 m/m, achieving the V-0 classification. Furthermore, its thermal degradation characteristics reveal a notably higher carbon residue rate. Additionally, the sound insulation capability has been significantly enhanced, with an average sound insulation level of 43.48 dB. This study provides a promising solution for enhancing the fire safety and acoustic properties of building sealing materials.

摘要

在建筑物中使用传统密封材料会带来重大的火灾和噪音污染风险。为了解决这些问题,我们提出了一种新型复合功能密封胶,旨在提高消防安全和隔音性能。该密封胶采用了一种独特的四组分填料体系,由层状双氢氧化物(LDHs)修饰的碳纳米管(CNTs)、磷酸二氢铵(ADP)和人造大理石废粉(AMWP)组成,即CLAA。碳纳米管/层状双氢氧化物框架提供结构支撑并增强热稳定性,而ADP层作为保护屏障,在燃烧过程中释放不可燃气体。AMWP颗粒通过产生阻抗失配来有助于隔音。所得的复合功能密封胶表现出改善的机械性能。在阻燃性方面,它的最低热释放峰值速率(PHRR)为224.83 kW/m,总烟雾释放量(TSR)为981.14 m/m,达到V-0级。此外,其热降解特性显示出明显更高的残炭率。此外,隔音能力得到了显著增强,平均隔音水平为43.48 dB。本研究为提高建筑密封材料的消防安全和声学性能提供了一个有前景的解决方案。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e90/11722415/c028165a8ad8/materials-18-00062-g001.jpg

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