Tan Chen, Si Guifu, Zou Chen, Chen Changle
Institutes of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, Anhui, 230601, China.
State Key Laboratory of Precision and Intelligent Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, 230026.
Angew Chem Int Ed Engl. 2025 Mar 17;64(12):e202424529. doi: 10.1002/anie.202424529. Epub 2025 Jan 28.
Polyolefins are simple hydrocarbons that require additional chemical modifications or functional additives to give them custom functions. Recent research in the development of functional polyolefins has surpassed the traditional approach of simply improving surface properties by incorporating polar moieties. Creating custom functionalized polyolefins by using specific functional units has attracted increasing attention. This review summarizes advances in preparing custom functionalized polyolefin materials using functional units such as comonomers, chain-transfer agents, post-polymerization modification reagents, and functional fillers. Exploring new functional units and innovative synthetic strategies will further enhance the performance and expand the applications of functional polyolefins.
聚烯烃是简单的碳氢化合物，需要额外的化学改性或功能添加剂才能赋予它们定制功能。功能聚烯烃开发方面的最新研究已经超越了通过引入极性部分来简单改善表面性能的传统方法。使用特定功能单元制备定制功能化聚烯烃引起了越来越多的关注。本文综述了使用共聚单体、链转移剂、后聚合改性试剂和功能填料等功能单元制备定制功能化聚烯烃材料的研究进展。探索新的功能单元和创新的合成策略将进一步提高功能聚烯烃的性能并扩大其应用范围。
