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湿热处理对甘薯淀粉模拟糊化过程中多尺度结构演变的影响

Multi-scale structural evolution during simulated gelatinization process of sweet potato starch by heat-moisture treatment.

作者信息

Zhang Sijie, Wu Weiguo, Zhu Jihe, Wu Junling, Gan Zengpeng, Deng Houqin, Zhang Yu, Liao Luyan

机构信息

College of Food Science and Technology, Hunan Agricultural University, Changsha 410128, China.

School of Food and Pharmacy, Shanghai Zhongqiao Vocational and Technical University, Shanghai 201514, China.

出版信息

Food Chem X. 2024 Dec 24;25:102123. doi: 10.1016/j.fochx.2024.102123. eCollection 2025 Jan.

DOI:10.1016/j.fochx.2024.102123
PMID:39830000
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11741091/
Abstract

The changes in properties and structures of raw sweet potato starch (RAW-SPS) and heat-moisture treatment (HMT) sweet potato starch (HMT-SPS) during gelatinization process (S1-S6) was investigated to elucidate the improvement effect of HMT on SPS. It was found that SPS exhibited the characteristics of pseudoplastic fluids, characterized by shear thinning and thixotropy, belonged to the C-type starch crystal. The gelatinization temperature of SPS was increased to 82.55 °C by HMT. HMT-SPS had better viscoelasticity in S3-S6. The particle size was smaller than that of RAW-SPS during the gelatinization process. The starch paste of S2 was gelatinized by heating at 95 °C, and the original crystalline structure of the starch was destroyed, where layered structure formed by recrystallization was observed. HMT-SPS showed a clear polarization cross, while disappeared after S2. HMT also improved the ordering degree. The results explained the mechanism of changes in HMT modified starch during the gelatinization process.

摘要

研究了原甘薯淀粉(RAW-SPS)和湿热处理(HMT)甘薯淀粉(HMT-SPS)在糊化过程(S1-S6)中性质和结构的变化,以阐明HMT对甘薯淀粉的改善效果。结果表明,甘薯淀粉表现出假塑性流体的特性,具有剪切变稀和触变性,属于C型淀粉晶体。HMT使甘薯淀粉的糊化温度提高到82.55℃。HMT-SPS在S3-S6阶段具有更好的粘弹性。在糊化过程中,其粒径比RAW-SPS小。S2的淀粉糊在95℃加热下糊化,淀粉的原始晶体结构被破坏,观察到重结晶形成的层状结构。HMT-SPS呈现明显的偏光十字,在S2之后消失。HMT还提高了有序度。这些结果解释了HMT改性淀粉在糊化过程中的变化机制。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/a974cd8e5bfd/gr7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/70a13340d603/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/2f23c0a1b3c4/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/e43bb50cec5d/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/5c3265d4d85a/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/a84877fd5145/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/146922c1f3a3/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/a974cd8e5bfd/gr7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/70a13340d603/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/2f23c0a1b3c4/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/e43bb50cec5d/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/5c3265d4d85a/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/a84877fd5145/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/146922c1f3a3/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b5/11741091/a974cd8e5bfd/gr7.jpg

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