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使用FlowCam分析评估陶瓷膜过滤法作为化妆品配方中微塑料替代品的效果。

Evaluation of Ceramic Membrane Filtration for Alternatives to Microplastics in Cosmetic Formulations Using FlowCam Analysis.

作者信息

Kim Seung Yeon, Kim Soyoun, Park Chanhyuk

机构信息

Department of Environmental Science and Engineering, Ewha Womans University, Seoul 03760, Republic of Korea.

出版信息

Membranes (Basel). 2025 Jan 19;15(1):35. doi: 10.3390/membranes15010035.

Abstract

The rapid expansion of the cosmetics industry has significantly increased the adoption of alternative microplastics in response to increasingly stringent global environmental regulations. This study presents a comparative analysis of the treatment performance of silica powder and cornstarch-common alternatives for microplastics in cosmetics-using ceramic membrane filtration combined with flow imaging microscopy (FlowCam) to analyze particle behavior. Bench-scale crossflow filtration experiments were performed with commercially available alumina ceramic membranes. By analyzing high-resolution images from FlowCam, the transport and retention behaviors of the two microplastic alternatives were examined by comparing their morphological properties. Despite their similar particle sizes, the cornstarch demonstrated a higher removal efficiency (82%) than the silica (72%) in the ceramic membrane filtration due to its greater tendency to aggregate. This increased tendency for aggregation suggests that cornstarch may contribute to faster fouling, while the stability and uniformity of silica particles result in less fouling. The FlowCam analysis revealed that the cornstarch particles experienced a slight increase in circularity and compactness over time, likely due to physical swelling and aggregation, while the silica particles retained their shape and structural integrity. These findings highlight the impact of the morphological properties of alternative microplastics on their filtration behavior and fouling potential.

摘要

随着全球环境法规日益严格,化妆品行业的迅速扩张显著增加了对替代性微塑料的采用。本研究对二氧化硅粉末和玉米淀粉(化妆品中微塑料的常见替代品)的处理性能进行了比较分析,采用陶瓷膜过滤并结合流动成像显微镜(FlowCam)来分析颗粒行为。使用市售氧化铝陶瓷膜进行了实验室规模的错流过滤实验。通过分析FlowCam的高分辨率图像,通过比较两种微塑料替代品的形态特性,研究了它们的传输和保留行为。尽管它们的粒径相似,但由于玉米淀粉更易聚集,在陶瓷膜过滤中其去除效率(82%)高于二氧化硅(72%)。这种增加的聚集趋势表明玉米淀粉可能导致更快的污染,而二氧化硅颗粒的稳定性和均匀性导致较少的污染。FlowCam分析显示,随着时间的推移,玉米淀粉颗粒的圆形度和紧实度略有增加,这可能是由于物理膨胀和聚集,而二氧化硅颗粒保持了其形状和结构完整性。这些发现突出了替代性微塑料的形态特性对其过滤行为和污染潜力的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35cf/11767035/a475d8d25d52/membranes-15-00035-g001.jpg

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