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用生物醋酸纤维素提高一氧化碳去除效率:一种多级膜分离方法。

Improving CO Removal Efficiency with Bio-Cellulose Acetate: A Multi-Stage Membrane Separation Approach.

作者信息

Khamwichit Attaso, Wongsuwan Kamontip, Dechapanya Wipawee

机构信息

Biomass and Oil Palm Research Center of Excellence, Walailak University, Thasala, Nakhon Si Thammarat 80160, Thailand.

Department of Chemical Engineering, School of Engineering and Technology, Walailak University, Thasala, Nakhon Si Thammarat 80160, Thailand.

出版信息

Polymers (Basel). 2025 Jan 17;17(2):224. doi: 10.3390/polym17020224.

Abstract

In this comprehensive investigation, the sustainable production and utilization of gas separation membranes derived from coconut water (CW) waste was investigated. The research focuses on the synthesis of bacterial cellulose (BC) and cellulose acetate (CA) membranes from CW, followed by a thorough analysis of their characteristics, including morphology, ATR-FTIR spectroscopy, tensile strength, and chemical composition. The study rigorously evaluates membrane performance, with particular emphasis on CO/CH selectivity under various operational conditions, including pressure, membrane thickness, and number of stages. The application of these membranes in gas separation units was optimized for CO/CH separation performance and eco-efficiency through a multi-stage membrane approach. The findings indicate that in double-stage configurations, CA membranes with a thickness of 0.04 mm, operating at 0.28 MPa, achieve a CO/CH selectivity of 35.52, significantly surpassing single-stage performance (selectivity: 19.72). Furthermore, eco-efficiency analysis reveals optimal performance at 0.04 mm thickness and 0.175 MPa, reaching 3.08 CO/CH selectivity/THB. These results conclusively demonstrate the viability of converting agricultural waste into high-performance gas separation membranes, representing a significant advancement in sustainable membrane technology. This research contributes valuable insights to the field and paves the way for further innovations in eco-friendly membrane production and application.

摘要

在这项全面的研究中,对源自椰子水(CW)废料的气体分离膜的可持续生产和利用进行了研究。该研究重点在于由椰子水合成细菌纤维素(BC)和醋酸纤维素(CA)膜,随后对其特性进行全面分析,包括形态、衰减全反射傅里叶变换红外光谱(ATR-FTIR)、拉伸强度和化学成分。该研究严格评估膜的性能,特别强调在包括压力、膜厚度和级数等各种操作条件下的CO/CH选择性。通过多级膜方法,对这些膜在气体分离装置中的应用进行了优化,以实现CO/CH分离性能和生态效率。研究结果表明,在双级配置中,厚度为0.04毫米、在0.28兆帕压力下运行的CA膜,其CO/CH选择性达到35.52,显著超过单级性能(选择性:19.72)。此外,生态效率分析表明,在厚度为0.04毫米、压力为0.175兆帕时性能最佳,CO/CH选择性/总热阻(THB)达到3.08。这些结果确凿地证明了将农业废料转化为高性能气体分离膜的可行性,代表了可持续膜技术的重大进步。这项研究为该领域提供了有价值的见解,并为环保型膜生产和应用的进一步创新铺平了道路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/06cf/11768582/c20335b92427/polymers-17-00224-g002.jpg

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