Efficient ternary organic solar cells with suppressed nonradiative recombination via B‒N based polymer donor.

Organic solar cells (OSCs) have developed rapidly in recent years. However, the energy loss ( ) remains a major obstacle to further improving the photovoltaic performance. To address this issue, a ternary strategy has been employed to precisely tune the and boost the efficiency of OSCs. The B‒N-based polymer donor has been proved to process high (T) and small Δ characters, which can inhibition of CT state recombination. Herin, B‒N-based polymer donor PBNT-BDD was incorporated into the state-of-the-art PM6:L8-BO binary to construct ternary OSCs. Together with the optimal morphology, the ternary device affords an impressive power conversion efficiency of 18.95% with an improved open-circuit voltage ( ), short-circuit density ( ), and reduced in comparison to the binary ones, which is the highest PCE for B‒N materials-based ternary device. This work broadens the selection of guest materials toward realizing the high performance of OSCs.