Chen Yan, Wang Xiaoyun, Huang Sili, Song Shiyi, Chen Shanjun, Hou Jie, Xiong Yan
School of Physics and Optoelectronic Engineering, Yangtze University, Jingzhou, 434023, P.R. China.
Phys Chem Chem Phys. 2025 Feb 12;27(7):3622-3633. doi: 10.1039/d4cp03914a.
Metamaterials hold great promise for application in the field of perfect absorbers due to their remarkable ability to manipulate electromagnetic waves. In this work, a full-spectrum ultra-wideband solar absorber with a multilayer metal-dielectric stacked structure is designed. Our absorber is simple and easy to manufacture, with Ti serving as the substrate, overlaid with SiN spacer layers and four pairs of Ti-SiN ring columns. It exhibits an average absorption rate of 98.48% from 280 to 4000 nm. The synergistic effects of cavity resonance (CR), surface plasmon resonance (SPR), and magnetic resonance (MR) effectively enhance the absorption performance. The impacts of different materials, stacked layers, and geometric parameters on the absorption performance are investigated, along with further analysis of the electromagnetic field distribution to study the physical mechanism for achieving high-efficiency absorption. Additionally, it is demonstrated that the absorber exhibits polarization-independent behavior under vertical incidence and maintains an average absorption rate of over 93% at a 50° incidence angle for transverse magnetic (TM) and transverse electric (TE) polarized light. Furthermore, the absorber achieves a total solar absorption rate of 98.07% across the entire spectrum, with a thermal radiation efficiency of over 99% and a photothermal conversion efficiency of 92.49% at 1000 K. To conclude, our absorber offers great possibilities for solar energy harvesting related applications.
超材料因其操纵电磁波的卓越能力,在完美吸收体领域具有巨大的应用前景。在这项工作中,设计了一种具有多层金属 - 电介质堆叠结构的全光谱超宽带太阳能吸收体。我们的吸收体简单易制造,以钛作为基底,上面覆盖有氮化硅间隔层和四对钛 - 氮化硅环形柱。它在280至4000纳米范围内的平均吸收率为98.48%。腔共振(CR)、表面等离子体共振(SPR)和磁共振(MR)的协同效应有效地提高了吸收性能。研究了不同材料、堆叠层数和几何参数对吸收性能的影响,并进一步分析了电磁场分布以研究实现高效吸收的物理机制。此外,结果表明该吸收体在垂直入射下表现出与偏振无关的特性,对于横磁(TM)和横电(TE)偏振光,在50°入射角时平均吸收率保持在93%以上。此外,该吸收体在整个光谱范围内的总太阳能吸收率达到98.07%,在1000 K时热辐射效率超过99%,光热转换效率为92.49%。总之,我们的吸收体为太阳能收集相关应用提供了巨大的可能性。