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用于工业染料检测的纳米发光揭秘洞察

An Insight Into Unveiling Nano Luminescence for Industrial Dye Detection.

作者信息

Safamariyam E, Synumol K P, Panicker Anu Jayanthi, Sha Mizaj Shabil, Roshan Shabnam, Dakua Sarada Prasad, Chandrasekar Vaisali, Singh Ajay Vikram, Sadasivuni Kishor Kumar

机构信息

Center for Advanced Materials, Qatar University, PO Box 2713, Doha, Qatar.

Department of Surgery, Hamad Medical Corporation (HMC), 3050, Doha, Qatar.

出版信息

J Fluoresc. 2025 Feb 7. doi: 10.1007/s10895-025-04151-y.

DOI:10.1007/s10895-025-04151-y
PMID:39918673
Abstract

Dye, a major contaminant from the textile, paper, and pulp industries, is a serious environmental and human health hazard. Because of their low cost, environmental friendliness, and sustainability, semiconductor nanoparticles are among the most effective photocatalysts for detecting dyes in wastewater. Quantum dots (QDs), particularly Carbon quantum dots (CQDs), have received a lot of attention due to their unique optical and electrical properties, making them excellent for applications such as sensing and detection. This paper describes a unique microwave-assisted method for synthesising CQDs in ambient reaction conditions, providing a fast, scalable, and passivation-free alternative to traditional methods. The CQDs were characterised using SEM, XRD, FTIR, UV-Vis spectrophotometry, and photoluminescence, which confirmed their uniform size distribution and outstanding optical characteristics. The CQDs had detection limits of 0.413 ppm for cresol red and 0.847 ppm for cresol purple, indicating great sensitivity and selectivity over a wide pH range. These findings propose a new, sustainable, and cost-effective alternative for tackling water pollution and its detrimental effects on aquatic ecosystems, hence increasing the use of Carbon QDs in environmental restoration.

摘要

染料是纺织、造纸和制浆工业的主要污染物,对环境和人类健康构成严重危害。半导体纳米颗粒因其成本低、环境友好和可持续性,是检测废水中染料最有效的光催化剂之一。量子点(QDs),特别是碳量子点(CQDs),因其独特的光学和电学性质而备受关注,使其非常适合用于传感和检测等应用。本文描述了一种在环境反应条件下合成CQDs的独特微波辅助方法,为传统方法提供了一种快速、可扩展且无需钝化的替代方法。使用扫描电子显微镜(SEM)、X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、紫外可见分光光度法和光致发光对CQDs进行了表征,证实了它们均匀的尺寸分布和出色的光学特性。CQDs对甲酚红的检测限为0.413 ppm,对甲酚紫的检测限为0.847 ppm,表明在很宽的pH范围内具有很高的灵敏度和选择性。这些发现为解决水污染及其对水生生态系统的有害影响提出了一种新的、可持续且具有成本效益的替代方案,从而增加了碳量子点在环境修复中的应用。

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Microwave Synthesis of Carbon Quantum Dots from Arabica Coffee Ground for Fluorescence Detection of Fe, Pb, and Cr.以阿拉比卡咖啡渣为原料微波合成碳量子点用于铁、铅和铬的荧光检测
ACS Omega. 2024 Apr 24;9(18):20571-20581. doi: 10.1021/acsomega.4c02254. eCollection 2024 May 7.
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Sci Rep. 2024 Apr 30;14(1):9915. doi: 10.1038/s41598-024-60726-y.
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