Tiwari Dilip Kumar, Ghosh Tapan Kumar, Gopinathan Anju Vakakuzhiyil, Gangavarapu Ranga Rao
Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036, Tamil Nadu, India.
Environ Sci Pollut Res Int. 2025 Feb 10. doi: 10.1007/s11356-025-36030-1.
Urea oxidation reaction (UOR) has been identified as a promising method for hydrogen production and the remediation of urea-rich wastewater by electrochemical techniques. In the present work, Ni/C and Ni@MoC(x)/C electrocatalysts (x = 0.1, 0.2, 0.4, and 0.6 mol fraction of MoC in Ni@MoC) are prepared by ball milling method followed by annealing at 800 °C for 2 h under nitrogen atmosphere. Electrooxidation of urea is carried out using these electrocatalysts in an alkaline solution. Among them, the Ni@MoC(0.4)/C catalyst shows a maximum current density of 96.5 mA cm at 1.7 V (versus RHE) in 1 M KOH and 0.33 M urea electrolyte. The Ni@MoC(0.4)/C catalyst exhibits better catalytic activity, low overpotential, and charge transfer resistance with extremely low Tafel slope compared to other compositions for UOR. The synergistic electronic effect between Ni and MoC components is responsible for generating active sites and facilitating the catalytic activity of UOR. The Ni@MoC(x)/C electrocatalysts are promising for treating urea-rich wastewaters and for use as a substitute for suppressing OER in water-splitting reactions.
