Ou Yang, Zhang Yifan, Luo Wen, Wu Yang, Wang Yong
Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444, P. R. China.
Macromol Rapid Commun. 2025 May;46(9):e2401149. doi: 10.1002/marc.202401149. Epub 2025 Feb 12.
Photocatalytic production of hydrogen peroxide (HO) represents a significant approach to achieving sustainable energy generation through solar energy, addressing both energy shortages and environmental pollution. Among various photocatalytic materials, covalent organic frameworks (COFs) have gained widespread attention and in-depth research due to their unique advantages, including high porosity, predesignability, and atomic-level tunability. In recent years, significant progress has been made in the development, performance enhancement, and mechanistic understanding of COF-based photocatalysts. This review focuses on the latest advancements in photocatalytic HO production using COFs, particularly emphasizing the rational design of COF structures to regulate catalytic performance and exploring the fundamental processes involved in photocatalysis. Based on current research achievements in this field, this paper also discusses existing challenges and future opportunities, aiming to provide a reference for the application of COFs in photocatalytic HO production.
光催化产过氧化氢（HO）是通过太阳能实现可持续能源生产的重要途径，可解决能源短缺和环境污染问题。在各种光催化材料中，共价有机框架（COF）因其独特优势，包括高孔隙率、可预设计性和原子级可调性，而受到广泛关注并得到深入研究。近年来，基于COF的光催化剂在开发、性能提升和机理理解方面取得了显著进展。本综述聚焦于使用COF进行光催化产HO的最新进展，特别强调COF结构的合理设计以调控催化性能，并探索光催化过程中的基本机制。基于该领域目前的研究成果，本文还讨论了现有挑战和未来机遇，旨在为COF在光催化产HO中的应用提供参考。
