Deciphering Mechanisms of CO-Selective Recognition over Acetylene within Porous Materials.

Reverse adsorption of carbon dioxide (CO) from acetylene (CH) presents both significant importance and formidable challenges, particularly in the context of carbon capture, energy efficiency, and environmental sustainability. In this Review, we delve into the burgeoning field of reverse CO/CH adsorption and separation, underscoring the absence of a cohesive materials design strategy and a comprehensive understanding of the CO-selective capture mechanisms from CH, in contrast to the quite mature methodologies available for CH-selective adsorption. Focusing on porous materials, the latest advancements in CO-selective recognition mechanisms are highlighted. The review establishes that the efficacy of CO recognition from CH relies intricately on a myriad of factors, including pore architecture, framework flexibility, functional group interactions, and dynamic responsive behaviors under operating conditions. It is noted that achieving selectivity extends beyond physical sieving, necessitating meticulous adjustments in pore chemistry to exploit the subtle differences between CO and CH. This comprehensive overview seeks to enhance the understanding of CO-selective recognition mechanisms, integrating essential insights crucial for the advancement of future materials. It also lays the groundwork for innovative porous materials in CO/CH separation, addressing the pressing demand for more efficient molecular recognition within gas separation technologies.