New Insight into a Green Process for Iron Manganese Ore Utilization: Efficient Separation of Manganese and Iron Based on Phase Reconstruction by Vanadium Recycle.

The difficulty of separating iron and manganese is a bottleneck issue in the traditional utilization process of iron manganese ore (Fe-Mn ore). In this work, ammonium polyvanadate (APV), an intermediate product in the vanadium industry, was introduced innovatively to convert the manganese-containing phase in Fe-Mn ore into manganese pyrovanadate (MnVO) and iron and manganese were then separated efficiently through the acid leaching process. The migration of manganese, iron, and vanadium were systematically studied through XRD, SEM, and leaching experiments. Results show that during the mixed roasting process of Fe-Mn ore and APV, VO, the decomposition product of APV, reacts with the decomposition product of manganese minerals in Fe-Mn ore, MnO, to produce the target product, acid-soluble MnVO. Iron and silicon exist in the form of FeO and SiO like in Fe-Mn ore. After the two-step leaching process of the sample roasted at 850 °C with (MnO)/(VO) of 2.25, the leaching ratios of manganese, iron and vanadium are 84.57%, 0.046%, and 4.68%, respectively, achieving the efficient separation of manganese with iron and vanadium. MnCO obtained by carbonization and precipitation from the manganese-containing leaching solution can be used as an intermediate product of manganese metallurgy or manganese chemical industry. APV obtained by alkaline leaching and precipitation from the vanadium- and iron-containing tailing can be recycled into the roasting system as the roasting additive. The TFe content in the iron-containing tailing reaches 57.21 wt.%, which meets the requirement of iron concentrate. More than 99 wt.% of vanadium from the additive APV can be recovered and recycled back into the Fe-Mn ore utilization process by APV recycling and wastewater recycling, making the Fe-Mn ore utilization with APV roasting a green process.