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用于改善有机污染物光降解的ZnO/r-GO复合光催化剂的构建

Construction of ZnO/r-GO Composite Photocatalyst for Improved Photodegradation of Organic Pollutants.

作者信息

Ding Yun, Qin Wenzhen, Zhu Huihua, Dai Yuhua, Hong Xiaowei, Han Suqin, Xie Yu

机构信息

School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China.

Yangxin County Special Education School, Binzhou 310000, China.

出版信息

Molecules. 2025 Feb 21;30(5):1008. doi: 10.3390/molecules30051008.

Abstract

In this work, a simple hydrothermal method was used to prepare a series of ZnO/r-GO (ZGO-x) catalysts. The obtained products were subjected to a series of characterizations, which showed that the zinc oxide particles were deposited onto r-GO and that the crystal structure was not disrupted. In addition, due to the large specific surface area and the good electrical conductivity of r-GO, more photogenerated electrons can be rapidly transferred from ZnO to r-GO to participate in the reaction, thus improving the photocatalytic performance. The degradation rate of the ZGO-3 sample reached 100% for RhB after simulated sunlight irradiation for 150 min, whereas the pure ZnO degraded RhB by about 83% under the same environment. ZGO-3 also showed the best photocatalytic degradation of methyl orange, with 100% degradation in 180 min, whereas pure ZnO degraded only 87.64% of methyl orange under solar irradiation.

摘要

在本工作中,采用一种简单的水热法制备了一系列ZnO/r-GO(ZGO-x)催化剂。对所得产物进行了一系列表征,结果表明氧化锌颗粒沉积在r-GO上,且晶体结构未被破坏。此外,由于r-GO具有较大的比表面积和良好的导电性,更多的光生电子能够迅速从ZnO转移到r-GO上参与反应,从而提高了光催化性能。在模拟太阳光照射150分钟后,ZGO-3样品对罗丹明B的降解率达到100%,而在相同环境下纯ZnO对罗丹明B的降解率约为83%。ZGO-3对甲基橙也表现出最佳的光催化降解效果,在180分钟内降解率为100%,而在太阳辐射下纯ZnO仅降解了87.64%的甲基橙。

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