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钒与选定金属离子与π-供体席夫碱配体的配位聚合物——合成、晶体结构及应用

Coordination Polymers of Vanadium and Selected Metal Ions with ,-Donor Schiff Base Ligands-Synthesis, Crystal Structure, and Application.

作者信息

Osypiuk Dariusz, Bartyzel Agata, Cristóvão Beata

机构信息

Department of General and Coordination Chemistry and Crystallography, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Skłodowska University in Lublin, Maria Curie-Skłodowska sq. 2, 20-031 Lublin, Poland.

出版信息

Molecules. 2025 Feb 27;30(5):1104. doi: 10.3390/molecules30051104.

DOI:10.3390/molecules30051104
PMID:40076327
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11901807/
Abstract

This review provides an overview of the synthesis, characterization and application of coordination polymers based on ,-donor Schiff base ligands. The coordination polymers (CPs) represent a novel class of inorganic-organic hybrid materials with tunable compositions and fascinating structures. They are composed of metal ions and organic ligands. Therefore, the nature of the metal ion and type of organic ligand is the most significant factor in constructing targeted coordination polymers with the desired properties. Due to the versatile coordination modes, ,-donor Schiff base ligands are also used to construct various CPs.

摘要

本综述概述了基于π-供体席夫碱配体的配位聚合物的合成、表征及应用。配位聚合物（CPs）是一类新型的无机-有机杂化材料，其组成可调且结构迷人。它们由金属离子和有机配体组成。因此，金属离子的性质和有机配体的类型是构建具有所需性能的目标配位聚合物的最重要因素。由于其多样的配位模式，π-供体席夫碱配体也被用于构建各种配位聚合物。

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