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采用电子束辐照合成的聚(丙烯酸)-海藻酸钠高吸水性水凝胶——第三部分:其在土壤中降解情况的评估

Poly(Acrylic Acid)-Sodium Alginate Superabsorbent Hydrogels Synthesized Using Electron-Beam Irradiation-Part III: An Evaluation of Their Degradation in Soil.

作者信息

Manaila Elena, Calina Ion Cosmin, Dumitru Marius, Craciun Gabriela

机构信息

Electron Accelerators Laboratory, National Institute for Laser, Plasma and Radiation Physics, 409 Atomistilor St., 077125 Magurele, Romania.

出版信息

Molecules. 2025 Feb 28;30(5):1126. doi: 10.3390/molecules30051126.


DOI:10.3390/molecules30051126
PMID:40076349
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11901601/
Abstract

Global challenges in agriculture, in terms of water and nutrient loss control, require new approaches to maintaining or even increasing crop production. Promising materials, such as superabsorbent hydrogels of hybrid types obtained from natural polymers grafted with synthetic polymers, represent a viable solution to solve these problems and maintain a clean environment. In view of this, two types of hydrogels based on sodium alginate, acrylic acid and polyethylene oxide obtained using 5.5 MeV electron-beam irradiation were subjected to degradation through burial in the soil. Swollen hydrogels in two types of water (distilled and tap) and two types of nutrient solutions (synthetic nutrient solution and 100% natural organic nutrient solution), with different pHs of 5.40, 6.05, 7.45 and 7.66, were buried in soil for 30 and 60 days and then extracted and analyzed in terms of their mass loss, swelling behavior and cross-linking structure. The highest mass losses after both 30 and 60 days were recorded for the hydrogels buried in soils whose humidity was maintained by watering them with the basic solutions (tap water and the organic nutrient solution). Structural modifications associated with the degradation process were highlighted by decreases in the cross-link densities and increases in the mesh sizes and swelling. These results were confirmed using FTIR and SEM techniques.

摘要

农业在水和养分流失控制方面面临的全球挑战,需要新的方法来维持甚至提高作物产量。一些有前景的材料,比如由天然聚合物接枝合成聚合物得到的混合型高吸水性水凝胶,是解决这些问题并维持环境清洁的可行方案。鉴于此,对通过5.5兆电子伏特电子束辐照获得的两种基于海藻酸钠、丙烯酸和聚环氧乙烷的水凝胶进行了土壤掩埋降解实验。将在两种水(蒸馏水和自来水)以及两种营养液(合成营养液和100%天然有机营养液)中溶胀的水凝胶,在不同pH值(5.40、6.05、7.45和7.66)下,埋入土壤30天和60天,然后取出并分析其质量损失、溶胀行为和交联结构。在30天和60天后,埋入用基本溶液(自来水和有机营养液)浇水以保持湿度的土壤中的水凝胶质量损失最高。交联密度降低、网孔尺寸增大和溶胀增加突出了与降解过程相关的结构变化。这些结果通过傅里叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)技术得到了证实。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/bc61be95efae/molecules-30-01126-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/e2c51a6acda0/molecules-30-01126-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/2ed5d6daef8a/molecules-30-01126-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/9da894aeaefa/molecules-30-01126-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/83a613136844/molecules-30-01126-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/4dfb83f9237d/molecules-30-01126-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/4bb32b7505d1/molecules-30-01126-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/23a5bf3529dd/molecules-30-01126-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/4d568d0a3412/molecules-30-01126-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/bc61be95efae/molecules-30-01126-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/e2c51a6acda0/molecules-30-01126-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/2ed5d6daef8a/molecules-30-01126-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/9da894aeaefa/molecules-30-01126-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/83a613136844/molecules-30-01126-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/4dfb83f9237d/molecules-30-01126-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/4bb32b7505d1/molecules-30-01126-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/23a5bf3529dd/molecules-30-01126-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/4d568d0a3412/molecules-30-01126-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/715f/11901601/bc61be95efae/molecules-30-01126-g009.jpg

相似文献

[1]
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[2]
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[3]
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[4]
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[5]
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[6]
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本文引用的文献

[1]
Poly(acrylic acid)-Sodium Alginate Superabsorbent Hydrogels Synthesized by Electron-Beam Irradiation-Part II: Swelling Kinetics and Absorption Behavior in Various Swelling Media.

Gels. 2024-9-23

[2]
The Influence of the Structural Architecture on the Swelling Kinetics and the Network Behavior of Sodium-Alginate-Based Hydrogels Cross-Linked with Ionizing Radiation.

Gels. 2024-9-12

[3]
Superabsorbent hydrogels based on natural polysaccharides: Classification, synthesis, physicochemical properties, and agronomic efficacy under abiotic stress conditions: A review.

Int J Biol Macromol. 2024-2

[4]
Natural Polymer-Based Hydrogels: From Polymer to Biomedical Applications.

Pharmaceutics. 2023-10-23

[5]
Experimental and theoretical studies on nitrate removal using epichlorohydrin-modified cross-linked chitosan derived from shrimp waste.

Environ Sci Pollut Res Int. 2023-10

[6]
Significance of biopolymer-based hydrogels and their applications in agriculture: a review in perspective of synthesis and their degree of swelling for water holding.

RSC Adv. 2023-8-18

[7]
Poly(Acrylic Acid)-Sodium Alginate Superabsorbent Hydrogels Synthesized by Electron Beam Irradiation Part I: Impact of Initiator Concentration and Irradiation Dose on Structure, Network Parameters and Swelling Properties.

Materials (Basel). 2023-6-23

[8]
NaAlg-g-AA Hydrogels: Candidates in Sustainable Agriculture Applications.

Gels. 2023-4-7

[9]
Sodium Alginate-g-acrylamide/acrylic Acid Hydrogels Obtained by Electron Beam Irradiation for Soil Conditioning.

Int J Mol Sci. 2022-12-21

[10]
Agricultural Applications of Superabsorbent Polymer Hydrogels.

Int J Mol Sci. 2022-12-1

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