Manaila Elena, Calina Ion Cosmin, Dumitru Marius, Craciun Gabriela
Electron Accelerators Laboratory, National Institute for Laser, Plasma and Radiation Physics, 409 Atomistilor St., 077125 Magurele, Romania.
Molecules. 2025 Feb 28;30(5):1126. doi: 10.3390/molecules30051126.
Global challenges in agriculture, in terms of water and nutrient loss control, require new approaches to maintaining or even increasing crop production. Promising materials, such as superabsorbent hydrogels of hybrid types obtained from natural polymers grafted with synthetic polymers, represent a viable solution to solve these problems and maintain a clean environment. In view of this, two types of hydrogels based on sodium alginate, acrylic acid and polyethylene oxide obtained using 5.5 MeV electron-beam irradiation were subjected to degradation through burial in the soil. Swollen hydrogels in two types of water (distilled and tap) and two types of nutrient solutions (synthetic nutrient solution and 100% natural organic nutrient solution), with different pHs of 5.40, 6.05, 7.45 and 7.66, were buried in soil for 30 and 60 days and then extracted and analyzed in terms of their mass loss, swelling behavior and cross-linking structure. The highest mass losses after both 30 and 60 days were recorded for the hydrogels buried in soils whose humidity was maintained by watering them with the basic solutions (tap water and the organic nutrient solution). Structural modifications associated with the degradation process were highlighted by decreases in the cross-link densities and increases in the mesh sizes and swelling. These results were confirmed using FTIR and SEM techniques.
农业在水和养分流失控制方面面临的全球挑战,需要新的方法来维持甚至提高作物产量。一些有前景的材料,比如由天然聚合物接枝合成聚合物得到的混合型高吸水性水凝胶,是解决这些问题并维持环境清洁的可行方案。鉴于此,对通过5.5兆电子伏特电子束辐照获得的两种基于海藻酸钠、丙烯酸和聚环氧乙烷的水凝胶进行了土壤掩埋降解实验。将在两种水(蒸馏水和自来水)以及两种营养液(合成营养液和100%天然有机营养液)中溶胀的水凝胶,在不同pH值(5.40、6.05、7.45和7.66)下,埋入土壤30天和60天,然后取出并分析其质量损失、溶胀行为和交联结构。在30天和60天后,埋入用基本溶液(自来水和有机营养液)浇水以保持湿度的土壤中的水凝胶质量损失最高。交联密度降低、网孔尺寸增大和溶胀增加突出了与降解过程相关的结构变化。这些结果通过傅里叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)技术得到了证实。
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