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壳聚糖@FeO纳米粒子修饰的丝网印刷石墨烯基电极在水培液和果汁中亚硝酸盐和抗坏血酸同时分析中的应用

Application of Chitosan@FeO Nanoparticle-Modified Screen-Printed Graphene-Based Electrode for Simultaneous Analysis of Nitrite and Ascorbic Acid in Hydroponics and Fruit Juice.

作者信息

Pitakrut Sudarut, Sanchayanukun Phetlada, Karuwan Chanpen, Muncharoen Sasithorn

机构信息

Department of Chemistry, Faculty of Science, Burapha University, Chonburi 20130, Thailand.

National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency (NSTDA), Pathum Thani 12120, Thailand.

出版信息

Sensors (Basel). 2025 Feb 26;25(5):1431. doi: 10.3390/s25051431.

Abstract

In this work, the development of screen-printed electrodes modified with chitosan-coated magnetite nanoparticles (CTS@FeO/SPGNE) for the simultaneous determination of nitrite (NO) and ascorbic acid (AA) is presented. The study investigated various ratios of graphene to chitosan-coated magnetite nanoparticles (CTS@FeO), as well as the optimal pH. These factors were examined due to their impact on the selectivity and sensitivity of the analysis. The results indicated that a graphene paste to CTS@FeO ratio of 16:1.0 g and a pH of 4 were optimal for the analysis of both NO and AA. Additionally, the behavior of the proposed electrode, its analytical performance, and interference studies were thoroughly examined. Furthermore, the CTS@FeO/SPGNE electrode shows potential for the simultaneous determination of NO and AA in hydroponics and fruit juice samples.

摘要

在本工作中,介绍了用于同时测定亚硝酸盐(NO)和抗坏血酸(AA)的壳聚糖包覆磁铁矿纳米颗粒修饰的丝网印刷电极(CTS@FeO/SPGNE)的研制。该研究考察了石墨烯与壳聚糖包覆磁铁矿纳米颗粒(CTS@FeO)的各种比例以及最佳pH值。由于这些因素对分析的选择性和灵敏度有影响,因此对其进行了研究。结果表明,石墨烯糊与CTS@FeO的比例为16:1.0 g且pH值为4时,对NO和AA的分析最为理想。此外,还对所提出电极的行为、其分析性能以及干扰研究进行了全面考察。此外,CTS@FeO/SPGNE电极在水培和果汁样品中同时测定NO和AA方面显示出潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9dcf/11902332/05ad2494d6ed/sensors-25-01431-g001.jpg

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