Enhancing electroluminescence performance of ultra-deep-blue through-space charge transfer emitters with CIE ≈ 0.05 methyl-modification.

Achieving efficient solution-processed ultra-deep-blue OLEDs remains a challenge. Herein, a methyl-modification strategy is proposed to overcome weak intramolecular charge transfer and the large energy gap between the singlet and triplet states (Δ ) of ultra-deep-blue through-space charge transfer (TSCT)-thermally activated delayed fluorescence (TADF) emitters. In this way, the reverse intersystem crossing (RISC) process is found to be effective from T to S and can be accelerated with the assistance of T. As a result, the ultra-deep-blue TSCT emitter 3MeCz-BO exhibits a minimized Δ of 0.02 eV, and an enhanced RISC rate of 3.71 × 10 s. Additionally, this modification can improve the solubility, enabling the fabrication of solution-processed organic light-emitting diodes (OLEDs). The maximum external quantum efficiency of the 3MeCz-BO-based solution-processed OLED reaches 10.1%, with a Commission Internationale de L'Eclairage (CIE) coordinates of (0.151, 0.051) and a luminance of 1334 cd m. This work is the first instance of developing high-performance ultra-deep-blue solution-processed TSCT-TADF OLEDs, which show comparable performance to vacuum-deposited OLEDs. Furthermore, the 3MeCz-BO-based OLED fits well within the standard Red Green Blue (sRGB) of CIE coordinates (0.15, 0.06), and is close to the CIE coordinates (0.131, 0.046) for the Rec. 2020 standard, implying its potential application in colorful display devices.