Zafar Ayesha, Majeed Adnan, Ahad Abdul, Iqbal Muhammad Adnan, Bokhari Tanveer Hussain, Mushtaq Zanira, Ali Shahzaib
Department of Chemistry, University of Agriculture Faisalabad Faisalabad-38000 Pakistan
Department of Chemistry, Government College University Faisalabad Faisalabad-38000 Pakistan
RSC Adv. 2025 Mar 18;15(11):8367-8384. doi: 10.1039/d4ra08833f. eCollection 2025 Mar 17.
Achieving carbon neutrality and slowing down global warming requires research into the electrochemical CO reduction reaction (CORR), which produces useful compounds. Utilizing renewable energy to meet carbon-neutral energy goals produces single-carbon (C) and multi-carbon (C) goods. Efficient and selective electrocatalysts are essential to advancing this revolutionary technology; bimetallic Fe-based catalysts work better than their monometallic counterparts because multiple metals work synergistically to reduce CO levels. A thorough summary of recent developments in the synthesis of Fe-X bimetallic catalysts will be provided in this review, with an emphasis on key performance indicators like stability, faradaic efficiency, potential, current density, and primary product production. In addition, this analysis will look at representative instances of Fe bimetallic catalysts that are well-known for their selectivity in generating particular alcohols and hydrocarbons, clarifying the mechanics behind CO reduction, pointing out existing difficulties, and examining the potential of electrosynthesis processes in the future.
实现碳中和和减缓全球变暖需要对电化学CO还原反应(CORR)进行研究,该反应可产生有用的化合物。利用可再生能源来实现碳中性能源目标可生产单碳(C)和多碳(C)产品。高效且具选择性的电催化剂对于推进这项革命性技术至关重要;双金属铁基催化剂比其单金属对应物表现更佳,因为多种金属协同作用以降低CO水平。本综述将全面总结Fe-X双金属催化剂合成方面的最新进展,重点关注稳定性、法拉第效率、电位、电流密度和主要产物生成等关键性能指标。此外,该分析将考察以生成特定醇类和烃类的选择性而闻名的铁双金属催化剂的代表性实例,阐明CO还原背后的机理,指出现有困难,并探讨未来电合成工艺的潜力。