• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

用于CO还原的铁基双金属电催化剂的合成进展。

Advances in the synthesis of Fe-based bimetallic electrocatalysts for CO reduction.

作者信息

Zafar Ayesha, Majeed Adnan, Ahad Abdul, Iqbal Muhammad Adnan, Bokhari Tanveer Hussain, Mushtaq Zanira, Ali Shahzaib

机构信息

Department of Chemistry, University of Agriculture Faisalabad Faisalabad-38000 Pakistan

Department of Chemistry, Government College University Faisalabad Faisalabad-38000 Pakistan

出版信息

RSC Adv. 2025 Mar 18;15(11):8367-8384. doi: 10.1039/d4ra08833f. eCollection 2025 Mar 17.

DOI:10.1039/d4ra08833f
PMID:40103975
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11915088/
Abstract

Achieving carbon neutrality and slowing down global warming requires research into  the electrochemical CO reduction reaction (CORR), which produces useful compounds. Utilizing renewable energy to meet carbon-neutral energy goals produces single-carbon (C) and multi-carbon (C) goods. Efficient and selective electrocatalysts are essential to advancing this revolutionary technology; bimetallic Fe-based catalysts work better than their monometallic counterparts because multiple metals work synergistically to reduce CO levels. A thorough summary of recent developments in the synthesis of Fe-X bimetallic catalysts will be provided in this review, with an emphasis on key performance indicators like stability, faradaic efficiency, potential, current density, and primary product production. In addition, this analysis will look at representative instances of Fe bimetallic catalysts that are well-known for their selectivity in generating particular alcohols and hydrocarbons, clarifying the mechanics behind CO reduction, pointing out existing difficulties, and examining the potential of electrosynthesis processes in the future.

摘要

实现碳中和和减缓全球变暖需要对电化学CO还原反应（CORR）进行研究，该反应可产生有用的化合物。利用可再生能源来实现碳中性能源目标可生产单碳（C）和多碳（C）产品。高效且具选择性的电催化剂对于推进这项革命性技术至关重要；双金属铁基催化剂比其单金属对应物表现更佳，因为多种金属协同作用以降低CO水平。本综述将全面总结Fe-X双金属催化剂合成方面的最新进展，重点关注稳定性、法拉第效率、电位、电流密度和主要产物生成等关键性能指标。此外，该分析将考察以生成特定醇类和烃类的选择性而闻名的铁双金属催化剂的代表性实例，阐明CO还原背后的机理，指出现有困难，并探讨未来电合成工艺的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/1a78fd8229ba/d4ra08833f-p7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/72cc544a5fac/d4ra08833f-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/8a151e89d7e0/d4ra08833f-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/cf626924baea/d4ra08833f-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/f58285882ffd/d4ra08833f-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/bf8c778293b2/d4ra08833f-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/5cf52d07cade/d4ra08833f-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/846d6fc9729b/d4ra08833f-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/202a8d87e369/d4ra08833f-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/6956483d56ef/d4ra08833f-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/acb1e755ed15/d4ra08833f-p2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/05fb446743ee/d4ra08833f-p3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/0dd28a3a4de4/d4ra08833f-p4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/97d1151e2926/d4ra08833f-p5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/edc50ad6a446/d4ra08833f-p6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/1a78fd8229ba/d4ra08833f-p7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/72cc544a5fac/d4ra08833f-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/8a151e89d7e0/d4ra08833f-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/cf626924baea/d4ra08833f-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/f58285882ffd/d4ra08833f-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/bf8c778293b2/d4ra08833f-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/5cf52d07cade/d4ra08833f-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/846d6fc9729b/d4ra08833f-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/202a8d87e369/d4ra08833f-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/6956483d56ef/d4ra08833f-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/acb1e755ed15/d4ra08833f-p2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/05fb446743ee/d4ra08833f-p3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/0dd28a3a4de4/d4ra08833f-p4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/97d1151e2926/d4ra08833f-p5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/edc50ad6a446/d4ra08833f-p6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af8b/11915088/1a78fd8229ba/d4ra08833f-p7.jpg

相似文献

1
Advances in the synthesis of Fe-based bimetallic electrocatalysts for CO reduction.用于CO还原的铁基双金属电催化剂的合成进展。
RSC Adv. 2025 Mar 18;15(11):8367-8384. doi: 10.1039/d4ra08833f. eCollection 2025 Mar 17.
2
Bimetallic Electrocatalysts for Carbon Dioxide Reduction.用于二氧化碳还原的双金属电催化剂
Chimia (Aarau). 2019 Nov 1;73(11):928-935. doi: 10.2533/chimia.2019.928.
3
Review on strategies for improving the added value and expanding the scope of CO electroreduction products.关于提高一氧化碳电还原产物附加值及拓展其范围的策略综述
Chem Soc Rev. 2024 May 20;53(10):5149-5189. doi: 10.1039/d3cs00857f.
4
Bimetallic Electrocatalysts for CO Reduction.双金属电催化剂用于 CO 还原。
Top Curr Chem (Cham). 2018 Oct 26;376(6):41. doi: 10.1007/s41061-018-0220-5.
5
Alloy Nanocatalysts for the Electrochemical Oxygen Reduction (ORR) and the Direct Electrochemical Carbon Dioxide Reduction Reaction (CO RR).用于电化学氧还原（ORR）和直接电化学二氧化碳还原反应（CO RR）的合金纳米催化剂。
Adv Mater. 2019 Aug;31(31):e1805617. doi: 10.1002/adma.201805617. Epub 2018 Dec 20.
6
Rational Design of Dual-Atom Catalysts for Electrochemical CO Reduction to C and C Products with High Activity and Selectivity: A Density Functional Theory Study.用于电化学CO还原为C和C产品的具有高活性和选择性的双原子催化剂的合理设计：密度泛函理论研究
Ind Eng Chem Res. 2025 Feb 18;64(8):4378-4387. doi: 10.1021/acs.iecr.4c04831. eCollection 2025 Feb 26.
7
Thermodynamic phase control of Cu-Sn alloy electrocatalysts for selective CO reduction.用于选择性CO还原的Cu-Sn合金电催化剂的热力学相控制
Nanoscale Horiz. 2024 Nov 19;9(12):2295-2305. doi: 10.1039/d4nh00393d.
8
Structural Regulating of Cu-Based Metallic Electrocatalysts for CO to C Products Conversion.用于CO转化为C产物的铜基金属电催化剂的结构调控
ChemSusChem. 2025 May 5;18(9):e202402184. doi: 10.1002/cssc.202402184. Epub 2025 Jan 9.
9
Recent Progress on Perovskite-Based Electrocatalysts for Efficient CO Reduction.用于高效CO还原的钙钛矿基电催化剂的最新进展
Molecules. 2023 Dec 18;28(24):8154. doi: 10.3390/molecules28248154.
10
Electrocatalytic CO Reduction to Alcohols: Progress and Perspectives.电催化将CO还原为醇类：进展与展望
Small Sci. 2024 Jun 11;4(8):2400129. doi: 10.1002/smsc.202400129. eCollection 2024 Aug.

本文引用的文献

1
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode.燃料电池阴极氧还原过电位的起源
J Phys Chem B. 2004 Nov 18;108(46):17886-17892. doi: 10.1021/jp047349j.
2
Spin states of metal centers in electrocatalysis.电催化中金属中心的自旋态
Chem Soc Rev. 2024 Aug 12;53(16):8123-8136. doi: 10.1039/d3cs00913k.
3
Electrocatalytic CO reduction to formate by a cobalt phosphino-thiolate complex.钴膦硫醇盐配合物电催化CO还原生成甲酸盐
Chem Sci. 2024 Feb 12;15(17):6385-6396. doi: 10.1039/d3sc06805f. eCollection 2024 May 1.
4
Towards Industrially Important Applications of Enhanced Organic Reactions by Microfluidic Systems.面向微流控系统增强有机反应在工业重要应用方面的研究
Molecules. 2024 Jan 13;29(2):398. doi: 10.3390/molecules29020398.
5
Efficient multicarbon formation in acidic CO reduction via tandem electrocatalysis.通过串联电催化在酸性CO还原中高效形成多碳产物
Nat Nanotechnol. 2024 Mar;19(3):311-318. doi: 10.1038/s41565-023-01543-8. Epub 2023 Nov 23.
6
Fe nanoparticles confined by multiple-heteroatom-doped carbon frameworks for aqueous Zn-air battery driving CO electrolysis.由多杂原子掺杂碳骨架限制的铁纳米颗粒用于水系锌空气电池驱动的CO电解。
J Colloid Interface Sci. 2024 Feb;655:176-186. doi: 10.1016/j.jcis.2023.10.157. Epub 2023 Nov 2.
7
Synergetic Role of Thermal Catalysis and Photocatalysis in CO Reduction on Cu/MoS.热催化与光催化在Cu/MoS上CO还原中的协同作用
J Phys Chem Lett. 2023 Sep 28;14(38):8421-8427. doi: 10.1021/acs.jpclett.3c01665. Epub 2023 Sep 15.
8
Does the Spin State and Oriented External Electric Field Boost the Efficiency of Fe(II) Pincer Catalyst toward CO Hydrogenation Reaction?自旋态和外电场是否能提高 Fe(II)夹持催化剂对 CO 加氢反应的效率？
Inorg Chem. 2023 Feb 6;62(5):2342-2358. doi: 10.1021/acs.inorgchem.2c04119. Epub 2023 Jan 23.
9
Bio-Inspired Bimetallic Cooperativity Through a Hydrogen Bonding Spacer in CO Reduction.通过氢键间隔基在一氧化碳还原中实现的生物启发型双金属协同作用
Angew Chem Int Ed Engl. 2023 Feb 13;62(8):e202214665. doi: 10.1002/anie.202214665. Epub 2023 Jan 11.
10
Keeping sight of copper in single-atom catalysts for electrochemical carbon dioxide reduction.关注用于电化学二氧化碳还原的单原子催化剂中的铜
Nat Commun. 2022 Apr 27;13(1):2280. doi: 10.1038/s41467-022-30027-x.