• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

钴膦硫醇盐配合物电催化CO还原生成甲酸盐

Electrocatalytic CO reduction to formate by a cobalt phosphino-thiolate complex.

作者信息

Intrator Jeremy A, Velazquez David A, Fan Sicheng, Mastrobattista Ellie, Yu Christine, Marinescu Smaranda C

机构信息

Department of Chemistry, University of Southern California Los Angeles CA 900089 USA

出版信息

Chem Sci. 2024 Feb 12;15(17):6385-6396. doi: 10.1039/d3sc06805f. eCollection 2024 May 1.

DOI:10.1039/d3sc06805f
PMID:38699267
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11062087/
Abstract

Electrochemical conversion of CO to value-added products serves as an attractive method to store renewable energy as energy-dense fuels. Selectivity in this type of conversion can be limited, often leading to the formation of side products such as H. The activity of a cobalt phosphino-thiolate complex ([Co(triphos)(bdt)]) towards the selective reduction of CO to formate is explored in this report. In the presence of HO, selective production of formate (as high as 94%) is observed at overpotentials of 750 mV, displaying negligible current degradation during long-term electrolysis experiments ranging as long as 24 hours. Chemical reduction studies of [Co(triphos)(bdt)] indicates deligation of the apical phosphine moiety is likely before catalysis. Computational and experimental results suggest a metal-hydride pathway, indicating an ECEC based mechanism.

摘要

将CO电化学转化为高附加值产品是一种将可再生能源存储为能量密集型燃料的有吸引力的方法。这种转化类型的选择性可能受到限制，常常导致副产物如H的形成。本报告探讨了钴膦硫醇配合物（[Co(triphos)(bdt)]）将CO选择性还原为甲酸盐的活性。在HO存在下，在750 mV的过电位下观察到甲酸盐的选择性生产（高达94%），在长达24小时的长期电解实验中，电流降解可忽略不计。[Co(triphos)(bdt)]的化学还原研究表明，顶端膦部分在催化之前可能发生脱配位。计算和实验结果表明存在金属氢化物途径，表明基于ECEC的机制。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/e7a91d2b0462/d3sc06805f-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/7688d6297dbd/d3sc06805f-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/594db7def2b7/d3sc06805f-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/8127d7ae17aa/d3sc06805f-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/e7257a0860ab/d3sc06805f-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/07cba8b096c2/d3sc06805f-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/9f684832822c/d3sc06805f-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/bbc3e609c211/d3sc06805f-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/bac0baf05fe0/d3sc06805f-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/e7a91d2b0462/d3sc06805f-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/7688d6297dbd/d3sc06805f-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/594db7def2b7/d3sc06805f-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/8127d7ae17aa/d3sc06805f-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/e7257a0860ab/d3sc06805f-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/07cba8b096c2/d3sc06805f-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/9f684832822c/d3sc06805f-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/bbc3e609c211/d3sc06805f-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/bac0baf05fe0/d3sc06805f-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5c/11062087/e7a91d2b0462/d3sc06805f-s3.jpg

相似文献

1
Electrocatalytic CO reduction to formate by a cobalt phosphino-thiolate complex.钴膦硫醇盐配合物电催化CO还原生成甲酸盐
Chem Sci. 2024 Feb 12;15(17):6385-6396. doi: 10.1039/d3sc06805f. eCollection 2024 May 1.
2
Electroreduction of CO to Formate with Low Overpotential using Cobalt Pyridine Thiolate Complexes.使用吡啶硫醇钴配合物将CO电还原为甲酸盐并具有低过电位
Angew Chem Int Ed Engl. 2020 Sep 1;59(36):15726-15733. doi: 10.1002/anie.202006269. Epub 2020 Aug 13.
3
Directing the reactivity of metal hydrides for selective CO reduction.指导金属氢化物的反应活性以实现 CO 选择性还原。
Proc Natl Acad Sci U S A. 2018 Dec 11;115(50):12686-12691. doi: 10.1073/pnas.1811396115. Epub 2018 Nov 21.
4
Switching Catalyst Selectivity via the Introduction of a Pendant Nitrophenyl Group.通过引入侧链硝基苯基改变催化剂选择性
Inorg Chem. 2022 Jan 24;61(3):1316-1326. doi: 10.1021/acs.inorgchem.1c02636. Epub 2022 Jan 12.
5
CoPO-Assisted Copper/Carbon Catalyst for Electrocatalytic Reduction of CO to Formate.CoPO 辅助的铜/碳催化剂用于电催化 CO 还原为甲酸盐。
ACS Nano. 2023 Jun 13;17(11):10055-10064. doi: 10.1021/acsnano.2c12426. Epub 2023 May 9.
6
Catalytic CO Reduction with Heptacoordinated Polypyridine Complexes: Switching the Selectivity via Metal Replacement.七配位多吡啶配合物催化一氧化碳还原：通过金属置换切换选择性
ChemSusChem. 2024 Feb 22;17(4):e202300737. doi: 10.1002/cssc.202300737. Epub 2023 Nov 13.
7
Understanding the Role of Inter- and Intramolecular Promoters in Electro- and Photochemical CO Reduction Using Mn, Re, and Ru Catalysts.理解锰、铼和钌催化剂在电和光化学 CO 还原中分子间和分子内促进剂的作用。
Acc Chem Res. 2022 Mar 1;55(5):616-628. doi: 10.1021/acs.accounts.1c00616. Epub 2022 Feb 8.
8
In Situ Bismuth Nanosheet Assembly for Highly Selective Electrocatalytic CO Reduction to Formate.原位铋纳米片组装用于将电催化一氧化碳高度选择性还原为甲酸盐
Chem Asian J. 2021 Jun 14;16(12):1539-1544. doi: 10.1002/asia.202100305. Epub 2021 May 10.
9
Homogeneous Electrochemical Reduction of CO to CO by a Cobalt Pyridine Thiolate Complex.钴吡啶硫醇盐配合物将CO均匀电化学还原为CO 。
Inorg Chem. 2020 Apr 20;59(8):5292-5302. doi: 10.1021/acs.inorgchem.9b03056. Epub 2020 Apr 8.
10
Renewable Formate from C-H Bond Formation with CO: Using Iron Carbonyl Clusters as Electrocatalysts.利用铁羰基簇作为电催化剂从 C-H 键形成 CO 中获得可再生的甲酸盐。
Acc Chem Res. 2017 Sep 19;50(9):2362-2370. doi: 10.1021/acs.accounts.7b00302. Epub 2017 Aug 24.

引用本文的文献

1
Generation of Formates Following 20 kHz Sonication of DSPE-mPEG2000 PEGylated Phospholipid Micelles.DSPE-mPEG2000聚乙二醇化磷脂微泡在20 kHz超声处理后甲酸盐的生成
Pharmaceutics. 2025 Aug 1;17(8):1008. doi: 10.3390/pharmaceutics17081008.
2
Advances in the synthesis of Fe-based bimetallic electrocatalysts for CO reduction.用于CO还原的铁基双金属电催化剂的合成进展。
RSC Adv. 2025 Mar 18;15(11):8367-8384. doi: 10.1039/d4ra08833f. eCollection 2025 Mar 17.

本文引用的文献

1
Electrocatalytic metal hydride generation using CPET mediators.用电感耦合等离子体介体进行电催化金属氢化物生成。
Nature. 2022 Jul;607(7919):499-506. doi: 10.1038/s41586-022-04874-z. Epub 2022 Jul 20.
2
Electronically-coupled redox centers in trimetallic cobalt complexes.三金属钴配合物中的电子耦合氧化还原中心。
Dalton Trans. 2022 Apr 5;51(14):5660-5672. doi: 10.1039/d1dt03404a.
3
Electrocatalytic syngas generation with a redox non-innocent cobalt 2-phosphinobenzenethiolate complex.使用氧化还原非惰性的2-膦基苯硫醇钴配合物进行电催化合成气生成。
Dalton Trans. 2021 Aug 21;50(31):10779-10788. doi: 10.1039/d0dt03270k. Epub 2021 Jul 21.
4
Improving and Understanding the Hydrogen Evolving Activity of a Cobalt Dithiolene Metal-Organic Framework.提高并理解二硫纶钴金属有机框架的析氢活性
ACS Appl Mater Interfaces. 2021 Apr 14;13(14):16384-16395. doi: 10.1021/acsami.1c01727. Epub 2021 Mar 31.
5
Biochemical and artificial pathways for the reduction of carbon dioxide, nitrite and the competing proton reduction: effect of 2 sphere interactions in catalysis.二氧化碳、亚硝酸盐和竞争质子还原的生物化学和人工途径：催化中 2 球相互作用的影响。
Chem Soc Rev. 2021 Mar 21;50(6):3755-3823. doi: 10.1039/d0cs01405b. Epub 2021 Jan 29.
6
Dirhodium complexes as electrocatalysts for CO reduction to HCOOH: role of steric hindrance on selectivity.作为将CO还原为HCOOH的电催化剂的二铑配合物：空间位阻对选择性的作用。
Chem Commun (Camb). 2021 Feb 14;57(13):1635-1638. doi: 10.1039/d0cc07659g. Epub 2021 Jan 19.
7
Hydrogenation and electrocatalytic reduction of carbon dioxide to formate with a single Co catalyst.用单一钴催化剂将二氧化碳氢化并电催化还原为甲酸盐
Chem Commun (Camb). 2020 Oct 13;56(81):12142-12145. doi: 10.1039/d0cc04310a.
8
Kinetic and mechanistic analysis of a synthetic reversible CO/HCO electrocatalyst.一种合成的可逆 CO/HCO 电催化剂的动力学和机理分析。
Chem Commun (Camb). 2020 Oct 27;56(85):12965-12968. doi: 10.1039/d0cc05556e.
9
A bioinspired molybdenum-copper molecular catalyst for CO electroreduction.一种用于CO电还原的仿生钼铜分子催化剂。
Chem Sci. 2020 May 18;11(21):5503-5510. doi: 10.1039/d0sc01045f. eCollection 2020 Jun 7.
10
Electroreduction of CO to Formate with Low Overpotential using Cobalt Pyridine Thiolate Complexes.使用吡啶硫醇钴配合物将CO电还原为甲酸盐并具有低过电位
Angew Chem Int Ed Engl. 2020 Sep 1;59(36):15726-15733. doi: 10.1002/anie.202006269. Epub 2020 Aug 13.